Multilayer Carrier Foil for Consistent Peeling and Pinhole Prevention

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Solution Overview

Problem

Conventional electrodeposited copper foils with carrier layers face issues such as varying peel strength, surface roughness, and pinholes, which affect the quality of ultra-thin copper foils used in printed circuit boards, leading to energy inefficiencies and inconsistent bonding during the manufacturing of miniaturized electronic components.

Innovation Solution

A multilayer carrier foil design comprising a copper carrier layer with a chromium release layer, an intermediate copper layer, an anti-migration layer, and an ultra-thin copper layer, which improves peeling consistency and prevents pinholes, enabling the production of high-quality printed circuit boards for miniaturized electronics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional carrier foil with release layer is used, then the ultra-thin copper foil can be formed, but the peeling strength varies widely and peeling consistency is poor

Engineering Contradiction:
Improvepeeling consistencyVSAvoidcarrier foil structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the carrier foil into multiple functional layers: a support layer (aluminum or copper), a release layer (metal oxide), and an intermediate layer (copper or alloy). This segmentation allows each layer to perform its specific function optimally, with the intermediate layer acting as a buffer to control peeling behavior and improve consistency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite material structures combining different metals and metal oxides in specific sequences. The combination of aluminum/copper support layer with metal oxide release layer and copper intermediate layer creates a composite structure that balances peeling performance with structural integrity.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the carrier foil surface roughness is high, then the ultra-thin copper foil can be formed, but the surface roughness of the copper foil increases affecting etching quality

Engineering Contradiction:
Improvecopper foil surface qualityVSAvoidcarrier foil production
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The intermediate layer acts as an intermediary between the carrier foil surface and the ultra-thin copper layer. It transfers the mechanical support function while providing a controlled surface that prevents direct transmission of carrier foil roughness to the copper layer, ensuring high surface quality for etching.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Use of energy by moving object

If laser drilling is used on shiny ultra-thin copper foil, then microvias can be created, but more energy is consumed due to laser reflection

Engineering Contradiction:
Improvelaser energy consumptionVSAvoidmicrovia drilling efficiency
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The patent modifies the surface optical properties of the ultra-thin copper foil through the release layer and surface treatment, changing its reflectivity characteristics. This reduces laser ray reflection and improves laser drilling efficiency by allowing better energy absorption.

Inventive Principle:
Principle #32Color changes

4Productivity

If the ultra-thin copper foil is made thinner to achieve micro-thin circuit patterns, then higher wiring density is achieved, but the foil becomes more susceptible to pinholes

Engineering Contradiction:
Improvewiring densityVSAvoidpinhole resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies different material compositions and thicknesses to different layers based on their specific functions. The intermediate layer uses specific copper alloys or compositions that provide pinhole resistance locally, while the ultra-thin copper layer maintains minimal thickness for high wiring density.

Inventive Principle:
Principle #3Local quality

5Strength

If high temperature compression is applied during lamination, then bonding is achieved, but the peeling strength becomes inconsistent due to oxidation-reduction reactions

Engineering Contradiction:
Improvebonding strengthVSAvoidpeeling strength consistency
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent performs preliminary surface treatment of the carrier foil and release layer before lamination to create stable surface conditions. This preliminary preparation prevents unwanted oxidation-reduction reactions during the high-temperature compression process, ensuring consistent peeling strength.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer carrier foil enhances the peeling process, reduces energy consumption, and ensures consistent bonding, facilitating the manufacture of high-density, precise circuitry in miniaturized electronic devices.

Implementation Method 1

a chromium release layer applied to the release side of the copper carrier layer

Methodology Applied
Scientific EffectRelease layer mechanism:

Implementation Method 2

an intermediate copper layer applied to the chromium release layer

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 3

an anti-migration layer applied to the intermediate copper layer

Methodology Applied
Scientific EffectAnti-migration barrier: Diffusion Barrier

Implementation Method 4

an ultra-thin copper layer applied to the anti-migration layer

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9955588B1Multilayer carrier foil
Publication Date: 2018.04.24 CHANG CHUN PETROCHEMICAL CO LTD
  • US9955588B1 patent drawing
  • US9955588B1 patent drawing
  • US9955588B1 patent drawing

AI summary

The present disclosure relates to a multilayer carrier foil, a core structure formed using the multilayer carrier foil, printed circuit boards, and electronic devices. The multilayer carrier foil comprises: (a) a copper carrier layer having a release side and a laminate side, the laminate side of carrier layer optionally having nodules; (b) a chromium release layer applied to the copper carrier layer; (c) an intermediate copper layer applied to the chromium release layer; (d) an anti-migration layer applied to the intermediate copper layer of (c); and (e) an ultra-thin copper layer applied to the anti-migration layer of (d). The disclosure further relates to methods of making the multi-layer carrier foil, the core structure, and printed circuit boards.