Multilayer Electronic Component Plating Film Heat Treatment

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Solution Overview

Problem

Existing multilayer electronic components face issues with solder wettability and contamination due to the thickness of paste electrode films, which reduces electrostatic capacity and lifespan under high-temperature and high-humidity conditions.

Innovation Solution

A method involving the formation of a continuous plating film on internal electrodes, followed by heat treatment at low oxygen partial pressure and high temperature, resulting in counter diffusion that seals voids and prevents moisture and contaminants from entering the laminate, using metals like Ni, Cu, or Ag for internal and plating films with different primary components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If paste electrode films are used to form external electrodes, then solder wettability is ensured, but the thickness of paste electrode films reduces the effective volume for electrostatic capacity

Engineering Contradiction:
Improvesolder wettabilityVSAvoideffective volume for electrostatic capacity
Core Design Contradiction:
ReliabilityVSVolume of stationary object

Solution Approach 1:

The patent changes the thickness parameter of the electrode structure by replacing the thick paste electrode film (several tens to hundreds of micrometers) with thin plating films (several micrometers), thereby increasing the effective volume for electrostatic capacity while maintaining the external electrode function

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite plating film structures (first plating film with Ni or other suitable material, and second plating film with Sn or other suitable material) to achieve both solder wettability and reduced thickness, combining the benefits of different materials in a layered configuration

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If electroless plating is used to deposit conductive metal layer on internal electrodes, then external electrodes can be formed directly, but bonding between internal electrodes and plating film is insufficient allowing moisture and contaminants to enter

Engineering Contradiction:
Improvedirect plating formationVSAvoidsealing property against moisture and contaminants
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies preliminary action by forming a specific paste electrode film structure before plating that promotes strong bonding, and by controlling firing conditions in advance to ensure proper adhesion between the internal electrodes and plating films, preventing future contamination

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces an intermediary mechanism through the paste electrode film that facilitates strong bonding between the internal electrodes and plating films, acting as a bonding promoter that prevents moisture and contaminant penetration

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances solder wettability, prevents contamination, and significantly improves sealing properties, extending the lifespan of multilayer electronic components under testing conditions.

Implementation Method 1

a plating step of forming a continuous plating film by depositing plating deposits on the edges of the internal electrodes exposed at the predetermined surface of the laminate which is prepared in the step of preparing a laminate and by performing plating growth of the plating deposits

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

a heat treatment step of performing a heat treatment on the laminate provided with the plating film at an oxygen partial pressure of about 5 ppm or less and at a temperature of about 600° C. or more

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

performing plating growth of the plating deposits so as to be connected to each other, and a heat treatment step of performing a heat treatment on the laminate provided with the plating film at an oxygen partial pressure of about 5 ppm or less and at a temperature of about 600° C. or more

Methodology Applied
Scientific EffectCounter diffusion: Diffusion

Data Source

PatentUS9536643B2Method for manufacturing multilayer electronic component
Publication Date: 2017.01.03 MURATA MFG CO LTD
  • US9536643B2 patent drawing
  • US9536643B2 patent drawing
  • US9536643B2 patent drawing

AI summary

A method for manufacturing a multilayer electronic component includes the steps of preparing a laminate including a plurality of laminated insulating layers and a plurality of internal electrodes disposed along interfaces between the insulating layers, edges of the internal electrodes being exposed at a predetermined surface of the laminate, and forming an external electrode on the predetermined surface to electrically connect exposed the edges of the internal electrodes. The step of forming an external electrode includes a plating step of forming a continuous plating film by depositing plating deposits on the edges of the internal electrodes exposed at the predetermined surface and by performing plating growth to be connected to each other, and a heat treatment step of performing a heat treatment at an oxygen partial pressure of about 5 ppm or less and at a temperature of about 600° C. or more.