Multilayer OCM Catalyst Segmentation for Scale-Up Selectivity

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Solution Overview

Problem

Conventional catalyst systems for oxidative coupling of methane (OCM) face challenges in maintaining high performance when scaled up, due to changes in pore structure leading to increased mass transfer resistance and decreased selectivity to desired products like C2+ hydrocarbons and C2H4, and struggles in providing the required strength, shape, and size for commercial applications.

Innovation Solution

A multilayer supported OCM catalyst composition featuring a structured multilayer supported multi-component rare earth metal oxides with a specific formulation (AaZbEcDdOx/alpha-Al2O3) that includes an alpha-alumina support, multiple oxide layers, and rare earth elements, enhancing crush strength and catalytic performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional catalyst systems are scaled up to large reactors, then production capacity increases, but selectivity towards desired products decreases due to pore structure changes and increased mass transfer resistance

Engineering Contradiction:
Improveproduction capacityVSAvoidselectivity towards desired products
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The catalyst is segmented into a multilayer structure with distinct functional zones: an outer layer containing the catalytically active material for high selectivity, and an inner core layer providing mechanical strength and structural stability. This segmentation allows the catalyst to maintain its performance characteristics when scaled up to large reactor sizes, as each layer independently optimizes for its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention employs a composite catalyst structure combining multiple materials with complementary properties: the outer layer uses materials optimized for catalytic activity and selectivity (such as perovskite structures or spinel oxides), while the inner core uses materials optimized for mechanical strength and thermal stability (such as alumina or magnesia). This composite approach resolves the contradiction between maintaining selectivity and achieving scalable production capacity.

Inventive Principle:
Principle #40Composite materials

2Strength

If catalysts are formed into pellets with required strength, shape and size for commercial applications, then mechanical properties improve, but performance decreases due to poor catalytic activity

Engineering Contradiction:
Improvemechanical strengthVSAvoidcatalytic performance
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The catalyst pellet is segmented into functional layers where the outer layer is optimized for catalytic performance with high surface area and active sites, while the inner core layer is optimized for mechanical strength. This segmentation allows the pellet to achieve both required mechanical properties for commercial handling and high catalytic performance, as each layer performs its designated function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the catalyst pellet are assigned different qualities: the outer layer has high porosity and surface area for catalytic activity, while the inner core has high density and strength for mechanical stability. This local differentiation of properties allows the overall catalyst to meet both mechanical strength requirements and catalytic performance requirements simultaneously.

Inventive Principle:
Principle #3Local quality

3Strength

If pore volume decreases to increase mechanical strength, then catalyst durability improves, but mass transfer resistance increases leading to reduced selectivity

Engineering Contradiction:
Improvecatalyst durabilityVSAvoidselectivity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The catalyst is segmented into an outer layer with high pore volume for mass transfer and selectivity, and an inner core with lower pore volume but high mechanical strength. This segmentation resolves the contradiction by allowing the outer layer to maintain high selectivity through adequate pore structure, while the inner core provides the mechanical durability needed for long-term operation, with each layer optimized for its primary function.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer supported OCM catalyst composition exhibits improved conversion, selectivity, activity, and stability compared to conventional catalysts, maintaining high performance even at larger scales by reducing mass transfer resistance and increasing crush strength.

Implementation Method 1

Multilayer supported oxidative coupling of the methane (OCM) catalyst compositions... for oxidative coupling of methane (OCM)... exhibits improved conversion, selectivity, activity, and stability compared to conventional catalysts

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11753357B2Multilayer mixed oxide supported catalyst for oxidative coupling of methane
Publication Date: 2023.09.12 SABIC GLOBAL TECHNOLOGIES BV
  • US11753357B2 patent drawing
  • US11753357B2 patent drawing

AI summary

A multilayer supported oxidative coupling of methane (OCM) catalyst composition (alpha-Al2O3 support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/alpha-Al2O3; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts alpha-Al2O3 support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; AaZbEcDdOx and Aa2Zb2Ec2Dd2Ox2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.