Nanoporous Carbon Energetic Composite With High Oxidizer Loading

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Solution Overview

Problem

Existing energetic materials face challenges in achieving high performance, safety, reactivity, and versatility, with industrial production being hindered by cost, toxicity, and limited applicability, particularly in nanoporous silicon and composite propellants.

Innovation Solution

A composite energetic material comprising a nanoporous carbonaceous material with a three-dimensional porosity structure, where at least 30% of the porosity is occupied by an inorganic oxidiser, allowing high adsorption and intermolecular interactions, resulting in a high oxidiser-to-fuel ratio, and produced through a simple impregnation method using a polar solvent.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If nanoporous silicon is used as fuel in composite energetic materials, then high performance is achieved, but cost increases and toxicity problems arise

Engineering Contradiction:
Improveenergetic performanceVSAvoidtoxicity and cost
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent replaces expensive and toxic nanoporous silicon with a disposable, low-cost, non-toxic organic polymer matrix that can be easily synthesized and processed. The polymer serves as a sacrificial fuel that decomposes completely during the energetic reaction, leaving no harmful residues.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the fundamental material parameter from inorganic nanoporous silicon to organic polymer, altering the chemical composition, porosity formation mechanism, and decomposition behavior while maintaining the nanoporous structure's energetic performance characteristics.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If micrometric particles are used in composite propellant, then ease of manufacture is maintained, but performance is limited

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcombustion performance
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent transitions from zero-dimensional micrometric particles to a three-dimensional interconnected nanoporous network structure within the polymer matrix. This dimensional transformation increases the surface area and porosity while maintaining macroscopic particle integrity, thereby improving combustion performance without sacrificing manufacturability.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent creates a composite structure combining organic polymer matrix with inorganic oxidizer particles, where the polymer provides structural integrity and porosity while the oxidizer provides energetic performance. This composite approach synergistically enhances both manufacturability and performance.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If nanoporous material with high porosity is used, then adsorption capacity increases, but mechanical strength decreases

Engineering Contradiction:
Improveoxidizer adsorption capacityVSAvoidmechanical properties
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent utilizes the inherent porosity of the organic polymer matrix, creating a three-dimensional network of nanoscale pores that provide high adsorption capacity for oxidizer particles. The polymer's molecular structure naturally forms this porous architecture, maintaining mechanical integrity while maximizing surface area for oxidizer loading.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material achieves high energetic performance, safety, and versatility, with improved mechanical properties and controlled reactivity, suitable for various applications including high explosives and propellant powders, while being cost-effective and environmentally friendly.

Implementation Method 1

at least 30% of the porosity is occupied by an inorganic oxidiser, allowing high adsorption

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

produced through a simple impregnation method

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 3

Pyrotechnic materials and propellant powders release energy via a deflagration process

Methodology Applied
Scientific EffectDeflagration: Deflagration

Implementation Method 4

explosives release energy via a detonation process

Methodology Applied
Scientific EffectDetonation: Detonation

Implementation Method 5

an energetic material is a material or mixture of materials capable of rapidly releasing energy via chemical reaction

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS12559443B2Energy-releasing composite material and method for manufacturing same
Publication Date: 2026.02.24 ECOLE ROYALE MILITAIRE
  • US12559443B2 patent drawing
  • US12559443B2 patent drawing
  • US12559443B2 patent drawing

AI summary

The invention relates to an energy-releasing composite material comprising at least one nanoporous material and at least one inorganic oxidant, characterised in that said nanoporous material is a nanoporous carbon material.