Planarizing Semiconductor Nanostructures with Solvent-Dissolvable Resist

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Solution Overview

Problem

Existing methods for planarizing nanostructures, such as nanowires, face challenges including inhomogeneous magnetization in ferromagnetic materials, electrical short-circuiting during metal electrode deposition, and difficulties in vertical integration, which hinder their application in spintronics and other nanotechnology fields.

Innovation Solution

A method involving the use of a solvent-dissolvable resist layer to embed nanostructures, followed by wafer bonding and selective removal of the resist layer, allowing for planarization and vertical integration of nanostructures without mechanical damage or electrical short-circuiting, enabling precise alignment and connection of nanostructures across multiple layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thin metal layers are used for electrically contacting nanowires, then electrical contact is achieved, but shadowing effects during directed deposition interrupt the metal layer and prevent complete contact

Engineering Contradiction:
Improveelectrical contact reliabilityVSAvoiddeposition process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The nanowires are planarized by embedding them in a planarization layer before the metal electrode deposition process. This preliminary planarization action ensures that the subsequent metal layer can be deposited uniformly without shadowing effects, allowing complete electrical contact across the entire electrode area.

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If ferromagnetic materials are used for spin-polarized current injection, then spintronics functionality is enabled, but inhomogeneous alignment of local magnetization and domain formation occur

Engineering Contradiction:
Improvespintronics application capabilityVSAvoidmagnetization alignment precision
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The nanowire surface is planarized before depositing the ferromagnetic material. This preliminary planarization prevents inhomogeneous magnetization alignment and domain formation during subsequent magnetization processes, enabling reliable spintronics applications with uniform magnetic properties across the entire electrode area.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If reactive ion etching is used to remove oxide layer after HSQ planarization, then nanowire exposure is achieved, but etching time must be precisely adjusted for each nanowire diameter and surface properties are negatively influenced

Engineering Contradiction:
Improvenanowire exposure precisionVSAvoidetching process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The mechanical/chemical etching process is replaced with a selective dissolution process using a solvent that specifically removes the water-soluble polymer resist layer without affecting the nanowire surface or requiring precise timing control. This substitution eliminates the complexity of monitoring etching progress and adjusting parameters for different nanowire diameters.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Manufacturing precision

If CMP is used for vertical integration, then planarization is achieved, but structural integrity of nanowires is affected

Engineering Contradiction:
Improvevertical integration precisionVSAvoidnanowire structural integrity
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

A water-soluble polymer resist layer is introduced as an intermediary between the nanowire and the planarization process. This intermediary layer absorbs the mechanical stress of planarization, allowing subsequent layers to be stacked vertically with nanometer precision while the nanowire itself remains protected and structurally intact.

Inventive Principle:
Principle #24Intermediary (Mediator)

5Manufacturing precision

If individual nanowire planarization is performed with oxide embedding, then planar surface is achieved, but only nanostructures with identical diameter can be optimally planarized simultaneously

Engineering Contradiction:
Improveplanarization precisionVSAvoidbatch processing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The water-soluble polymer resist layer serves as a universal planarization medium that can accommodate nanowires of varying diameters simultaneously. When dissolved, it creates a uniformly planar surface that optimally supports nanowires of different sizes, enabling batch processing of diverse nanostructures without requiring individualized treatment for each diameter.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables efficient planarization and vertical integration of nanostructures, allowing for reliable electrical contacting and preventing magnetization disruptions, facilitating their use in spintronics and other nanotechnology applications.

Implementation Method 1

The initial substrate is removed from the first layer using a solvent

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

applying a target substrate to the first layer

Methodology Applied
Scientific EffectWafer bonding: Welding

Data Source

PatentUS10714568B2Method for producing a flat free contacting surface for semiconductor nanostructures
Publication Date: 2020.07.14 FORSCHUNGSZENTRUM JULICH GMBH
  • US10714568B2 patent drawing
  • US10714568B2 patent drawing
  • US10714568B2 patent drawing

AI summary

A method for producing a planar free surface comprising embedded, contactable nanostructures includes arranging at least one nanostructure on a surface of an initial substrate; applying a first layer to the surface of the initial substrate, wherein the first layer embeds the at least one nanostructure; applying a target substrate to the first layer; and separating the initial substrate from the first layer such that the at least one nanostructure embedded in the first layer has a planar free surface. An additional layer is applied to the surface of the initial substrate before the at least one nanostructure is applied to the initial substrate, and in that the initial substrate is removed from the first layer using a solvent.