NDIR Gas Analyzer with Narrowband Filters for Coal Gas

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Solution Overview

Problem

Current methods for measuring coal gas components and calorific value are inaccurate, slow, and unable to perform real-time online analysis, particularly due to interference between gases, which prevents precise measurement of CH4, CnHm, CO, and H2, essential for energy contribution, and calculating the calorific value of coal gas.

Innovation Solution

The method optimizes NDIR narrowband filter parameters to simultaneously measure various gas components, including CH4, CnHm, CO, and CO2, using specific filter wavelengths to reduce interference, and converts other hydrocarbons into C3H8 for calorific value calculation, resulting in a more cost-effective and faster analysis compared to traditional methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If chromatographic analysis technique is used to analyze gas concentration, then multiple components can be analyzed through one-time sample injection, but it needs carrier gas, can only achieve intermittent measurement, and cannot achieve site measurement

Engineering Contradiction:
Improvecapability to analyze multiple gas componentsVSAvoidreal-time online measurement capability
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The patent combines multiple detection functions (TCD for H2, ECD for O2, NDIR for CO/CO2/CH4) into a single integrated detector system that shares common gas channels and sample injection pathways, enabling simultaneous real-time measurement of multiple gas components without requiring separate instruments or carrier gases

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The detector system is designed with multi-functional capabilities where a single instrument can perform thermal conductivity detection, electrochemical detection, and infrared detection simultaneously, allowing one device to replace multiple specialized instruments and achieve universal gas component analysis

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If NDIR method with narrowband filter is used to measure CH4 and CnHm, then gas concentration can be detected, but mutual interference between CnHm and CH4 prevents accurate measurement

Engineering Contradiction:
Improvedetection speedVSAvoidaccuracy of CH4 measurement
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent segments the infrared detection into multiple independent detection channels, each equipped with narrowband filters targeting specific wavelength ranges for different gases (CO at 4.6μm, CO2 at 2.3μm, CH4 at 3.3μm, CnHm at 3.4μm), allowing simultaneous detection while minimizing spectral interference through wavelength separation

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each gas detection channel uses customized narrowband filters with specific center wavelengths and bandwidths optimized for the target gas, creating locally optimized detection conditions for each component while maintaining overall system performance

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If TCD is used to measure H2 concentration, then hydrogen can be detected, but interference from CO2 and CH4 prevents accurate measurement without revision

Engineering Contradiction:
Improvehydrogen concentration measurementVSAvoidaccuracy of H2 measurement
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

The system implements feedback correction where TCD measurements of H2 are automatically adjusted based on simultaneous CO2 and CH4 concentration data from ECD and NDIR detectors, compensating for thermal conductivity interference and delivering accurate H2 measurements without manual intervention

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent introduces intermediate correction mechanisms where data from CO2 and CH4 detectors serve as mediators to correct the H2 measurement from TCD, using the known thermal conductivity characteristics of these gases to calculate and remove their interference effects from the H2 reading

Inventive Principle:
Principle #24Intermediary (Mediator)

4Measurement precision

If multiple independent instruments are used to measure different gas components, then each component can be measured with dedicated method, but system complexity and cost increase significantly

Engineering Contradiction:
Improveaccuracy of individual gas measurementVSAvoidnumber of instruments required
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent merges TCD, ECD, and NDIR detection technologies into a single integrated instrument with shared sample handling systems, gas channels, and data processing units, maintaining the measurement precision of each individual method while reducing the system from multiple separate instruments to one unified device

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The instrument is designed as a multi-functional platform capable of performing thermal conductivity detection, electrochemical detection, and infrared detection simultaneously through different detection channels, replacing multiple specialized instruments with a single universal analyzer

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for accurate, simultaneous measurement of multiple coal gas components, reduces interference, and calculates the calorific value efficiently, with a significantly lower manufacturing cost and analysis speed 30 times faster than conventional chromatographs.

Implementation Method 1

non-dispersive infrared technology

Methodology Applied
Scientific EffectNon-dispersive infrared absorption: Absorption (EM radiation)

Implementation Method 2

infrared gas analyzer

Methodology Applied
Scientific EffectInfrared radiation absorption: Infrared Radiation

Implementation Method 3

principle of thermal conductivity

Methodology Applied
Scientific EffectThermal conductivity: Conduction (thermal)

Implementation Method 4

measured with ECD

Methodology Applied
Scientific EffectElectrochemical detection: Electrochemiluminescence

Data Source

PatentEP2796856B1Coal gas component and calorific value measurement method
Publication Date: 2020.01.01 WUHAN CUBIC OPTOELECTRONICS CO LTD
  • EP2796856B1 patent drawingFigure 1
  • EP2796856B1 patent drawingFigure 2
  • EP2796856B1 patent drawingFigure 3

AI summary

A coal gas component and calorific value measurement method, comprising the following steps: utilizing a non-dispersive infrared technology, and selecting narrowband optical filters with the center wavelength (CWL)/half width bandwidth (HWBP) proportions of 4.66±0.05µm/90±5nm, 4.26±0.05µm/120±5nm, 7.85±0.05µm/180±5nm, and 3.46±0.05µm/120±5nm respectively to measure the volume concentrations of CO, CO2, CH4 and CnHm in the coal gas; utilizing a thermal-conductive gas sensor to measure the volume concentration of H2; utilizing an electro-chemical sensor to measure the volume concentration of 02; utilizing the measured CH4 value to correct the measured CnHm result; and utilizing the measured CO2 and CH4 values to correct the measured H2 result, thus obtaining the accurate CO, CH4, CnHm, H2, 02 content of the coal gas; and utilizing the measured CO and CH4 values and the corrected H2 and CnHm volume concentrations to calculate the calorific value of the coal gas. The present method achieves rapid and accurate measurement of the components and calorific value of multi-component coal gas with one apparatus.