Negative Developing Method High-Speed Spin Drying

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Solution Overview

Problem

The conventional negative developing method using organic solvents is costly due to high usage of cleaning liquids, leading to reduced development quality and difficulties in controlling circuit pattern line widths, as residual dissolved products often remain on the substrate.

Innovation Solution

A negative developing method involving a developer containing an organic solvent, where the substrate is spun at a high speed to remove the developer and dissolved products without cleaning liquid, followed by targeted rear face cleaning and drying at lower speeds to minimize liquid usage and maintain development quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a cleaning liquid containing organic solvent is supplied to the substrate surface to remove developer and dissolved products, then development quality is maintained, but cleaning liquid consumption increases significantly

Engineering Contradiction:
Improvedevelopment qualityVSAvoidcleaning liquid consumption
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The substrate cleaning process is segmented into two distinct stages: (1) spin-drying the front surface at high speed to remove developer and dissolved products without cleaning liquid, and (2) supplying cleaning liquid only to the rear face at low speed. This segmentation allows different cleaning strategies for different surfaces, reducing overall cleaning liquid consumption while maintaining development quality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different cleaning approaches are applied to different locations of the substrate: the front surface receives no cleaning liquid but is spun at high speed for mechanical removal, while the rear face receives cleaning liquid at low spin speed. This local differentiation optimizes cleaning liquid usage by applying it only where necessary.

Inventive Principle:
Principle #3Local quality

2Loss of substance

If the usage amount of cleaning liquid is decreased to reduce costs, then cleaning liquid consumption is reduced, but development quality deteriorates due to residual dissolved products

Engineering Contradiction:
Improvecleaning liquid consumptionVSAvoiddevelopment quality
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The high-speed spin-drying is performed as a preliminary action before any cleaning liquid is supplied. This preliminary mechanical removal of developer and dissolved products from the front surface reduces the burden on the cleaning liquid, allowing it to be used more efficiently and in smaller amounts while still achieving complete cleaning.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conventional chemical cleaning method (using cleaning liquid to dissolve and remove products) is partially replaced with a mechanical method (high-speed spinning to centrifugally remove developer and dissolved products). This substitution reduces dependence on cleaning liquid while maintaining cleaning effectiveness.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If cleaning liquid is supplied continuously to ensure complete removal of dissolved products, then development quality is maintained, but processing time increases

Engineering Contradiction:
Improvedevelopment qualityVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The cleaning process uses periodic action with distinct phases: a high-speed spin phase for mechanical removal, followed by a low-speed cleaning liquid supply phase. This periodic alternation between mechanical and chemical cleaning methods achieves complete cleaning more efficiently than continuous cleaning liquid supply, reducing overall processing time.

Inventive Principle:
Principle #19Periodic action

4Loss of substance

If high-speed spinning is used to remove developer without cleaning liquid, then cleaning liquid consumption is reduced, but control precision of development timing becomes difficult

Engineering Contradiction:
Improvecleaning liquid consumptionVSAvoiddevelopment timing control
Core Design Contradiction:
Loss of substanceVSMeasurement precision

Solution Approach 1:

The system uses feedback control to monitor the spin speed and timing, ensuring that the high-speed spin-drying phase is precisely controlled to remove developer without affecting development timing. The controller adjusts parameters based on process feedback to maintain both cleaning efficiency and development precision.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces cleaning liquid consumption, allows precise control of development timing, and prevents residual dissolved products from remaining on the substrate, thereby maintaining development quality and accurately controlling circuit pattern line widths.

Implementation Method 1

spinning the substrate at a first speed, the first speed being relatively higher... Spinning at higher speeds causes a relatively large centrifugal force to act on the developer on the resist film. Consequently, the developer can be removed from the surface of the substrate

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 2

the substrate is spun to be dried through a spin-dry effect

Methodology Applied
Scientific EffectSpin-dry effect: Centrifugal Force

Data Source

PatentUS9063429B2Negative developing method and negative developing apparatus
Publication Date: 2015.06.23 SCREEN SEMICON SOLUTIONS CO LTD
  • US9063429B2 patent drawing
  • US9063429B2 patent drawing
  • US9063429B2 patent drawing

AI summary

After a developing step, a substrate is spun at high speeds without supplying a cleaning liquid to a surface of the substrate. This causes a large centrifugal force to act on a developer on a resist film. Consequently, the developer can be removed rapidly from the surface of the substrate. As a result, development can be stopped at an expected timing. Moreover, a circuit pattern having an expected dimension can be obtained. At this time, a dissolved product is also removable with the developer from the substrate. This can avoid failure in development caused by the dissolved product. Consequently, suitably maintained quality of negative development can be achieved with a reduced usage amount of the cleaning liquid.