Near-infrared absorbing composition, near-infrared absorbing film, and image sensor for solid-state imaging element

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Solution Overview

Problem

Near-infrared absorbing compositions using copper complexes face issues with dispersion stability, particularly in water-containing systems, and existing solutions do not adequately address the aggregation of copper complexes when exposed to moisture or heat.

Innovation Solution

A near-infrared absorbing composition comprising a compound with a specific structure and a metal ion, where the compound is also used to form a metal complex with a copper compound, providing improved dispersion and stability through an ethylene oxide and alkyl-substituted ethylene oxide structure combination, along with a phosphonic acid compound for enhanced stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a phosphonic acid copper complex is used as a near-infrared absorbing agent, then near-infrared absorption performance is improved, but dispersion stability deteriorates when exposed to water or moisture

Engineering Contradiction:
Improvenear-infrared absorption performanceVSAvoiddispersion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces a specific solvent as an intermediary substance between the phosphonic acid copper complex and water. This solvent acts as a mediator that prevents direct interaction between the copper complex and water molecules, thereby maintaining dispersion stability while preserving near-infrared absorption performance. The solvent creates a protective environment that stabilizes the copper complex dispersion without compromising its optical properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the dispersion system by selecting a solvent with specific properties (likely hydrophobic or low water solubility). This parameter change in the solvent composition prevents water from causing aggregation of the copper complex, thus improving dispersion stability while maintaining the near-infrared absorption capability of the copper complex.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If copper complex concentration is increased to improve near-infrared absorption, then absorption performance is improved, but aggregation is accelerated by heat and moisture

Engineering Contradiction:
Improvenear-infrared absorption performanceVSAvoidaggregation under heat and moisture
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The solvent serves as a protective intermediary that allows higher concentrations of copper complex to be dispersed without immediate aggregation. By mediating the interaction between copper complex molecules and the environment (heat and moisture), the solvent enables increased copper complex concentration for better near-infrared absorption while preventing the harmful aggregation effect.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies beforehand cushioning by pre-selecting a solvent that provides protective effects against heat and moisture-induced aggregation before these harmful factors act on the copper complex. The solvent creates a stable dispersion environment in advance, cushioning the copper complex from aggregation even at higher concentrations and under thermal or humid conditions.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves good dispersion and stability of the copper complex, maintaining performance under moisture exposure and heat, leading to improved near-infrared absorption and resistance in solid imaging elements.

Implementation Method 1

a near-infrared absorbing composition with good dispersion of the metal complex, in particular the copper complex

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

a near-infrared absorbing composition comprising a compound with a specific structure and a metal ion, where the compound is also used to form a metal complex with a copper compound, providing improved dispersion and stability through an ethylene oxide and alkyl-substituted ethylene oxide structure combination

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 3

near-infrared absorbing composition, near-infrared absorbing film, and image sensor for solid-state imaging element

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS11971563B2Near-infrared absorbing composition, near-infrared absorbing film, and image sensor for solid-state imaging element
Publication Date: 2024.04.30 KONICA MINOLTA INC
  • US11971563B2 patent drawing
  • US11971563B2 patent drawing
  • US11971563B2 patent drawing

AI summary

Disclosed is a near-infrared absorbing composition, including: a near-infrared absorbing agent; and a solvent, wherein the near-infrared absorbing agent includes at least one of the following Component (A) and Component (B):Component (A): a component composed of a compound having a structure of the following general formula (I) and a metal ion;Component (B): a component composed of a metal complex that is obtainable by a reaction of the compound having the structure of the following general formula (I) and a metal compound.