Non-Planar Optical Coatings for Scratch-Resistant Anti-Reflection

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Solution Overview

Problem

Existing anti-reflective coatings on non-planar substrates are susceptible to abrasion and scratch damage, compromising optical performance and durability, particularly in electronic devices with curved surfaces, due to variations in viewing angles and mechanical properties.

Innovation Solution

A coated article with an optical coating having varying thickness and refractive index layers designed for non-planar substrates, ensuring hardness and optical consistency across different viewing angles, utilizing materials like SiO2, Al2O3, and diamond-like carbon to enhance scratch resistance and anti-reflectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If known anti-reflective coatings are used to improve optical performance, then light transmittance is improved and reflectance is reduced, but the coatings become susceptible to wear and abrasion

Engineering Contradiction:
Improvelight transmittanceVSAvoidabrasion resistance
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent employs composite material structures combining multiple dielectric layers with different refractive indices (e.g., SiO2, TiO2, Si3N4) to achieve both optical performance and mechanical durability. The composite nature allows optimization of both optical properties (low reflectance) and mechanical properties (hardness, abrasion resistance) that cannot be achieved with single materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coating system uses layers with locally optimized properties - softer low-refractive-index layers for optical performance and harder high-refractive-index layers for mechanical protection. This local differentiation of material properties throughout the coating thickness enables simultaneous achievement of optical and mechanical requirements.

Inventive Principle:
Principle #3Local quality

2Strength

If nitrides and diamond-like coatings are used to increase hardness, then scratch resistance is improved, but light transmittance is compromised

Engineering Contradiction:
ImprovehardnessVSAvoidlight transmittance
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent combines hard nitride layers (Si3N4, TiN) with transparent dielectric layers (SiO2, TiO2) in a composite structure. The nitride layers provide the required hardness and scratch resistance, while the transparent dielectric layers ensure adequate light transmittance. The multi-layer composite allows both properties to coexist.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Hardness is localized to specific layers (nitride layers) where mechanical protection is needed, while other layers (transparent dielectrics) maintain optical transparency. This spatial distribution of properties throughout the coating structure resolves the contradiction between hardness and transmittance.

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If coatings are applied to non-planar substrates to maintain optical performance, then viewing angle consistency is improved, but coating thickness uniformity becomes difficult to control

Engineering Contradiction:
Improvecolor consistencyVSAvoidcoating thickness uniformity
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by adjusting coating thickness as a function of position on the substrate. For non-planar substrates, the coating thickness is deliberately varied to compensate for surface curvature, ensuring that the optical path length remains consistent across different viewing angles. This controlled parameter variation maintains color consistency despite substrate non-planarity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating design incorporates dynamic adaptation to substrate geometry, where the optimal coating thickness is determined based on the local surface orientation and viewing angle requirements. This dynamic approach allows the coating to maintain consistent optical properties across curved or non-planar surfaces.

Inventive Principle:
Principle #15Dynamics

4Ease of manufacture

If single-layer anti-reflective coatings are used to simplify manufacturing, then process complexity is reduced, but optical performance and durability are compromised

Engineering Contradiction:
Improvecoating process simplicityVSAvoidoverall durability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent segments the anti-reflective coating into multiple functional layers, each with specific thickness and material properties optimized for particular functions (optical performance, mechanical protection, adhesion). This segmentation allows independent optimization of each layer's characteristics to achieve overall system performance that cannot be attained with a single layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The multi-layer structure uses composite materials with different refractive indices and mechanical properties. This composite approach enables simultaneous optimization of optical performance (through refractive index matching) and mechanical durability (through hardness and adhesion properties of different materials).

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coated article achieves high hardness (≥8 GPa) and maintains low reflectance (≤8%) with minimal color variation (≤10) across different viewing angles, enhancing durability and optical performance on non-planar surfaces.

Implementation Method 1

The optical coating has a thickness measured in the direction normal to the major surface of the substrate, wherein the thickness differs between portions of the optical coating disposed over the first portion and the second portion of the substrate

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

The optical coating forms an anti-reflective surface

Methodology Applied
Scientific EffectInterference: Interference

Implementation Method 3

The coated article exhibits at the first portion of the substrate and at the second portion of the substrate hardness of about 8 GPa or greater at an indentation depth of about 50 nm or greater

Methodology Applied
Scientific EffectHardness:

Data Source

PatentEP3482237B1Coatings of non-planar substrates and methods for the production thereof
Publication Date: 2026.03.04 CORNING INC
  • EP3482237B1 patent drawingFigure 1
  • EP3482237B1 patent drawingFigure 2~5
  • EP3482237B1 patent drawingFigure 6~8

AI summary

A coated article may comprise a substrate and an optical coating. The substrate may have a major surface comprising a first portion and a second portion. A first direction that is normal to the first portion of the major surface may not be equal to a second direction that is normal to the second portion of the major surface. The optical coating may be disposed on at least the first portion and the second portion of the major surface. The coated article may exhibit at the first portion of the substrate and at the second portion of the substrate hardness of about 8 GPa or greater at an indentation depth of about 50 nm or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test.