OLED Anode Segmentation for Electron Injection and Low Resistance

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Solution Overview

Problem

Existing organic light emitting diode (OLED) displays face challenges in achieving low resistance and reliable optical properties, which affect their efficiency and reliability, particularly due to issues with electron injection and light absorption.

Innovation Solution

The OLED display incorporates a first electrode with a stacked structure comprising layers of materials with a work function of 4.0 eV or less and low resistivity, such as ytterbium and silver, to enhance electron injection and reduce resistance, while maintaining low absorption optical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single-layer electrode structure is used, then the device complexity is reduced, but the resistance is high and electron injection is insufficient

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidelectrode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The electrode is divided into multiple functional layers: a first layer with low work function material (Yb, Ca, Ba, Sr) for electron injection, a second layer with low resistivity material (Al, Ag, Mo, W) for current conduction, and optionally a third layer with low work function material for protection and additional electron injection. This segmentation allows each layer to optimize its specific function, achieving both low resistance and high electron injection efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The electrode uses composite material structure combining different materials with complementary properties. The low work function materials (e.g., Yb, Ca, Ba, Sr) are combined with low resistivity metals (e.g., Al, Ag, Mo, W) to create an electrode that simultaneously achieves excellent electron injection capability and low electrical resistance, resolving the contradiction between injection efficiency and resistance.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If transparent conductive oxide is used, then light transmittance is improved, but resistance is high

Engineering Contradiction:
Improvelight transmittanceVSAvoidelectrical resistance
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The electrode combines transparent conductive oxide (ITO, IZO, IGZO) with low work function materials (Yb, Ca, Ba, Sr) and low resistivity metals (Al, Ag, Mo, W) in a composite structure. The transparent conductive oxide layer maintains light transmittance, while the low work function and low resistivity metal layers provide excellent electron injection and current conduction, respectively, achieving both optical transparency and low resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The electrode is segmented into multiple layers where the transparent conductive oxide layer handles light transmission, the low work function layer handles electron injection, and the low resistivity metal layer handles current conduction. This functional segmentation allows each layer to optimize its specific property without compromising the others.

Inventive Principle:
Principle #1Segmentation

3Reliability

If low work function material is used, then electron injection is improved, but light absorption increases

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidlight absorption
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The electrode is segmented so that the low work function material layer is positioned specifically at the interface with the emission layer to maximize electron injection, while the low resistivity metal layer with better optical properties handles the bulk current conduction. This spatial segmentation allows the low work function material to perform its injection function without excessive light absorption in the light-emitting path.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The low work function material (Yb, Ca, Ba, Sr) is applied locally at the electrode-emission layer interface where electron injection is needed, rather than throughout the entire electrode structure. This localized application provides high electron injection efficiency at the critical interface while minimizing overall light absorption in the electrode.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in an OLED display with improved reliability, low resistance, and efficient light emission characteristics, suitable for both small and large portable devices, with reduced light absorption and increased durability.

Implementation Method 1

a first layer comprising a material having a work function of about 4.0 eV or less and an electron injection material

Methodology Applied
Scientific EffectElectron injection: Thermionic Emission

Implementation Method 2

a second layer comprising a material having a resistivity of about 10 μΩcm or less

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

light emission is achieved by energy generated when exitons, produced by combination of electrons and holes, drop from the exited state to the ground state

Methodology Applied
Scientific EffectLight emission: Electroluminescence

Data Source

PatentUS8735876B2Organic light emitting diode display
Publication Date: 2014.05.27 SAMSUNG DISPLAY CO LTD
  • US8735876B2 patent drawing
  • US8735876B2 patent drawing
  • US8735876B2 patent drawing

AI summary

An organic light emitting diode display, which includes: a first electrode; a second electrode facing the first electrode; and an emission layer interposed between the first electrode and the second electrode. Herein the first electrode includes: a first layer including a material having a work function of about 4.0 eV or less and an electron injection material; and a second layer including a material having a resistivity of about 10 μΩcm or less. The first layer is disposed between the second layer and the emission layer.