Dual Emission OLED Cathode Selective Deposition

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Solution Overview

Problem

Existing organic light-emitting display devices face challenges in patterning the cathode electrode for dual emission structures, particularly in achieving efficient light emission and luminance efficiency while maintaining transparency to external light.

Innovation Solution

The use of a selective deposition method for the top electrode using an open mask, where the adhesive force of the metal vapor to the auxiliary layers differs, allowing for the formation of a dual emission structure with varying electrode thicknesses and layer configurations to reduce exciton quenching and enhance luminance efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a fine metal mask is used for patterning the cathode electrode in dual emission structures, then the light emission pattern can be controlled, but the manufacturing complexity and cost increase significantly

Engineering Contradiction:
Improvecathode electrode pattern precisionVSAvoidpatterning process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Instead of using a metal mask to block metal deposition where the cathode should not be formed, the patent inverts the approach by using an organic auxiliary layer to selectively attract metal vapor deposition. The auxiliary layer is applied only in regions where the cathode electrode should be formed, and the metal vapor is deposited without a mask, allowing the metal to selectively adhere to the auxiliary layer regions.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent introduces an organic auxiliary layer as an intermediary substance between the metal vapor source and the substrate. This auxiliary layer acts as a mediator that selectively attracts and binds metal vapor molecules, enabling patterned cathode formation without requiring a physical metal mask. The auxiliary layer is subsequently removed, leaving the desired electrode pattern.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Length of stationary object

If the cathode electrode is formed close to the organic emitting layer to improve device structure, then the device thickness is reduced, but exciton quenching occurs which reduces luminance efficiency

Engineering Contradiction:
Improvedevice thicknessVSAvoidluminance efficiency
Core Design Contradiction:
Length of stationary objectVSLoss of energy

Solution Approach 1:

The patent introduces an organic intermediate layer as a mediator between the cathode electrode and the organic emitting layer. This intermediate layer serves as a buffer that prevents direct contact between the electrode and the emitting layer, thereby avoiding exciton quenching while maintaining a compact device structure. The intermediate layer is subsequently removed, but it has already fulfilled its protective function during the deposition process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent performs a preliminary action by forming the cathode electrode pattern before removing the auxiliary layer. The auxiliary layer is applied, metal vapor is deposited selectively on it, and then the auxiliary layer is removed - all before forming the final device structure. This preliminary patterning action allows subsequent layers to be formed without requiring continuous mask usage.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If multiple patterning masks are used to form different electrode patterns, then the manufacturing precision is improved, but the manufacturing time and process complexity increase

Engineering Contradiction:
Improveelectrode pattern accuracyVSAvoidmanufacturing throughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent inverts the conventional masking approach by eliminating the need for multiple metal masks. Instead of using masks to define where electrodes should NOT be formed, the method uses organic auxiliary layers to define where electrodes SHOULD be formed. This allows all electrode patterns to be formed in a single metal vapor deposition step without sequential masking operations.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The organic auxiliary layer serves multiple functions: it acts as a pattern definition layer, a deposition template, and a temporary protective layer. By applying different auxiliary layers to different regions, the method can simultaneously define patterns for multiple electrodes (first electrode, second electrode, third electrode) in a single metal deposition process, eliminating the need for multiple separate patterning steps.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of organic light-emitting display devices with improved luminance efficiency, dual emission capabilities, and transparency to external light, while simplifying the manufacturing process by eliminating the need for additional patterning masks.

Implementation Method 1

forming a fourth electrode within the first area via a vacuum deposition technique by applying a vapor that includes a metal for forming the fourth electrode to a top surface of the first auxiliary layer within the first area and a top surface of the second auxiliary layer within the second area

Methodology Applied
Scientific EffectSelective deposition: Deposition (physical)

Implementation Method 2

An adhesive force of the fourth electrode with respect to the first auxiliary layer may be greater than an adhesive force of the fourth electrode with respect to the second auxiliary layer

Methodology Applied
Scientific EffectAdhesive force difference: Adhesive

Implementation Method 3

An organic light emitting display device is a self-emissive display including an organic compound that is electrically exited to emit light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9293515B2Organic light-emitting display device and method of manufacturing the same
Publication Date: 2016.03.22 SAMSUNG DISPLAY CO LTD
  • US9293515B2 patent drawing
  • US9293515B2 patent drawing
  • US9293515B2 patent drawing

AI summary

An organic light-emitting display device and a method of manufacturing the organic light-emitting display device. The organic light-emitting display device is a dual emission display capable of displaying differing images on either side of the display, and includes a facing electrode that is selectively deposited in the first area but not in the second area, the selectivity being brought about by a varying an underlying material having differing adhesive forces with the material of the facing electrode. In addition, the underlying materials of the facing electrode and other intermediate layers of the organic light emitting diode device provide extra distance between the organic light emitting layer and a reflective electrode, so that exciton quenching is reduced, resulting in improved light emitting efficiency.