OLED Coating Composition for Uniform Solvent-Resistant Thin Films

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Solution Overview

Problem

Existing organic light emitting devices manufactured through deposition processes suffer from material loss and inefficiencies, requiring materials that can be used in a solution process to form stable, uniform thin films with high coatability and solvent resistance, while maintaining excellent current efficiency and service life characteristics.

Innovation Solution

A compound represented by Formula 1, which includes fluoro groups and oxygen or sulfur atoms, is used in a coating composition to form a stable thin film through heat or light treatment, enabling a solution process for manufacturing organic light emitting devices with improved hole injection layers, enhancing hole mobility and service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a deposition process is used to manufacture organic light emitting devices, then material loss occurs frequently, but a solution process is needed to increase production efficiency

Engineering Contradiction:
Improveproduction efficiencyVSAvoidmaterial loss
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent replaces the mechanical deposition process with a solution-based chemical process. The compound is dissolved in a solvent to form a coating composition that can be applied via solution processing methods, eliminating material loss associated with deposition while maintaining device performance

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical state of the material from solid deposit to dissolved solution. By controlling solubility parameters and using appropriate solvents, the material can be processed in solution form and then converted to functional film through solvent evaporation or heat treatment

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If commercialized materials for deposition process are used, then good crystallinity is achieved, but the material is not dissolved well in solution and crystals are easily formed

Engineering Contradiction:
ImprovecrystallinityVSAvoidsolubility
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent introduces specific functional groups (fluoro groups and oxygen or sulfur atoms) at particular positions in the molecular structure. This local modification improves solubility in specific regions of the molecule without compromising the overall crystallinity and light-emitting properties of the material

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite molecular structure combining hydrophobic aromatic cores with hydrophilic functional groups (fluoro groups, oxygen-containing or sulfur-containing groups). This composite structure achieves both good solubility in organic solvents and maintained crystallinity for device performance

Inventive Principle:
Principle #40Composite materials

3Loss of substance

If a solution process is used, then material loss is reduced, but uniform thin film formation without holes or aggregation is difficult

Engineering Contradiction:
Improvematerial lossVSAvoidthin film uniformity
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent optimizes solution parameters including solvent type, concentration, and additives to control film formation. The molecular structure is designed to prevent aggregation in solution while maintaining order during film formation, achieving uniform thin films without holes or defects

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses solvents and potentially additives as intermediaries to facilitate uniform film formation. The coating composition includes the compound dissolved in appropriate solvents that enable smooth film deposition and prevent aggregation during the coating process

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If layers are made resistant to solvents and materials used in other layer formation, then solvent resistance is improved, but excellent current efficiency and service life must be maintained

Engineering Contradiction:
Improvesolvent resistanceVSAvoidcurrent efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent designs a composite molecular structure with fluorinated and oxygen/sulfur-containing groups that provide both solvent resistance and excellent charge transport properties. The molecular architecture balances hydrophobicity for solvent resistance with electron-rich regions for current efficiency

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent places solvent-resistant functional groups (fluoro groups) at specific positions while maintaining electron-transporting regions elsewhere in the molecule. This local differentiation achieves both solvent resistance for layer stability and high current efficiency for device performance

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound allows for large-area device production with low driving voltage, high light emitting efficiency, and extended service life by increasing hole mobility and providing solvent resistance, thus overcoming the limitations of deposition processes.

Implementation Method 1

A compound represented by Formula 1, which includes fluoro groups and oxygen or sulfur atoms, is used in a coating composition to form a stable thin film through heat or light treatment

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS12528764B2Compound, coating composition comprising same, organic light-emitting device using same, and manufacturing method therefor
Publication Date: 2026.01.20 LG CHEM LTD
  • US12528764B2 patent drawing
  • US12528764B2 patent drawing
  • US12528764B2 patent drawing

AI summary

The present specification relates to a compound of Formula 1, a coating composition comprising the same, an organic light emitting device formed by using the same, and a method for manufacturing the same,wherein all the variables are described herein.