Organic Light-Emitting Device Compounds for Low Voltage and Long Lifespan

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving low driving voltage and high efficiency while maintaining a long lifespan due to limitations in carrier transport and molecular aggregation.

Innovation Solution

The use of specific compounds represented by Formulae A to D in the organic layer, including a fluorescent host and dopant, which enhance hole transport capability, thermal stability, and bipolar carrier transport characteristics, reducing electron leakage and improving interface stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice performance
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the chemical structure of organic compounds by introducing specific moieties (Formulae A to D) with tailored electronic properties. This changes the energy levels, carrier mobility, and HOMO/LUMO parameters of the emission layer materials, enabling lower driving voltage operation while maintaining efficient charge transport and recombination.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite organic layer structures combining multiple compounds with complementary functions: hole transport materials, electron transport materials, fluorescent hosts, and phosphorescent dopants. This composite approach optimizes both carrier transport balance and light emission efficiency, resolving the contradiction between low voltage and high performance.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic compounds are used in the emission layer, then light emission occurs, but molecular aggregation reduces efficiency and lifespan

Engineering Contradiction:
Improveemission efficiencyVSAvoidmolecular aggregation
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent introduces compounds with specific local molecular structures (Formulae A to D) that possess particular steric properties and intermolecular interaction characteristics. These local structural features prevent excessive molecular aggregation while maintaining optimal packing for efficient energy transfer, thus improving emission efficiency without sacrificing compositional stability.

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If emission efficiency is improved, then brightness increases, but device lifespan decreases due to material degradation

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent optimizes the energy level parameters (HOMO, LUMO, triplet energy) of the organic compounds to achieve balanced electron-hole injection and recombination. This parameter optimization improves emission efficiency while the stable molecular structures resist degradation, extending device lifespan.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses small-molecule organic compounds that can be precisely synthesized with controlled purity and stability characteristics. These compounds provide efficient emission with improved long-term operational stability compared to conventional materials.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in improved emission efficiency, reduced molecular aggregation, and extended lifespan of the organic light-emitting device by optimizing carrier transport and stability.

Implementation Method 1

the second compound is a fluorescent host and the third compound is a fluorescent dopant

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

enhance hole transport capability, thermal stability, and bipolar carrier transport characteristics

Methodology Applied
Scientific EffectCarrier transport: Conduction (electrical)

Data Source

PatentUS20210184119A1Organic light-emitting device
Publication Date: 2021.06.17 SAMSUNG DISPLAY CO LTD
  • US20210184119A1 patent drawing
  • US20210184119A1 patent drawing
  • US20210184119A1 patent drawing

AI summary

An organic light-emitting device including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer. The organic layer includes a first compound and the emission layer includes a second compound and a third compound. The second compound is a fluorescent host, the third compound is a fluorescent dopant, and the first compound, the second compound, and the third compound each independently includes at least one selected from moieties represented by Formulae A to D: