OLED Emission Layer Dopant Energy Level Control

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Solution Overview

Problem

Existing organic light-emitting devices face inefficiencies and reduced lifespan due to imbalances in energy levels and emission spectra, particularly at specific wavelengths, affecting their overall performance and stability.

Innovation Solution

Incorporating a host and dopant configuration in the organic light-emitting device where the dopant satisfies specific energy level conditions and the host includes compounds like phosphine oxide-based, pyrimidine-containing, and cyano group-containing materials, optimizing the emission layer to achieve balanced energy transfer and improved electroluminescence spectra.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then basic light emission is achieved, but efficiency and lifespan are reduced due to imbalanced energy levels and emission spectra

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the energy level difference between dopant singlet and triplet states (|ES1-ET1|≤0.2 eV) and selecting specific host compounds (phosphine oxide-based, pyrimidine-containing, triazine-containing, or cyano group-containing compounds). These parameter optimizations enable efficient energy transfer and balanced emission spectra, simultaneously improving light emission efficiency and device lifespan.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If energy levels are not optimized, then device structure is simpler, but emission spectrum balance and efficiency are poor

Engineering Contradiction:
Improveelectroluminescence efficiencyVSAvoidenergy level configuration complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes electroluminescence efficiency by changing the energy level parameters of the dopant (|ES1-ET1|≤0.2 eV) and selecting specific host compound classes. This parameter optimization achieves balanced emission spectra and high efficiency without requiring complex device structural modifications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the efficiency and stability of the organic light-emitting device by ensuring efficient energy transfer and maintaining a balanced emission spectrum, leading to improved performance and extended lifespan.

Implementation Method 1

the dopant satisfies Equation 1: |ED,S1−ED,T1|≤0.2 eV, wherein, in Equation 1, ED, S1 refers to a singlet state energy level (eV) of the dopant; and ED, T1 refers to a triplet state energy level (eV) of the dopant

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

an electroluminescence (EL) spectrum of the organic light-emitting device satisfies Equation 2 and Equation 3

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11450827B2Organic light-emitting device
Publication Date: 2022.09.20 SAMSUNG DISPLAY CO LTD
  • US11450827B2 patent drawing
  • US11450827B2 patent drawing
  • US11450827B2 patent drawing

AI summary

An organic light-emitting device is provided, including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode and comprising an emission layer, wherein the emission layer includes a host and a dopant, wherein the host includes at least one selected from a phosphine oxide-based compound, a pyrimidine-containing compound, a triazine-containing compound, and a cyano group-containing compound, and the dopant satisfies Equation 1, wherein, in Equation 1, ED, S1 refers to a singlet state energy level (eV) of the dopant; and ED, T1 refers to a triplet state energy level (eV) of the dopant:|ED,S1−ED,T1|≤0.2 eV.  Equation 1