OLED Emission Layer Dopants for Balanced Charge Injection

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Solution Overview

Problem

Existing organic light emitting diode (OLED) displays face challenges in achieving balanced hole and electron injection, leading to instability and reduced light emitting efficiency and lifespan due to imbalances in the organic layer.

Innovation Solution

Incorporating specific compounds represented by Chemical Formulas 1 to 3 as dopants in the emission layer, along with a structured layer configuration including a hole injection layer, hole transport layer, emission layer, electron transport layer, and electron injection layer, to facilitate balanced charge injection and recombination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic layer structure is used, then device simplicity is maintained, but charge injection balance is poor leading to reduced efficiency and lifespan

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoidorganic layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The organic layer is segmented into multiple functional sub-layers: hole injection layer, hole transport layer, emission layer, electron transport layer, and electron injection layer. Each sub-layer is optimized for its specific function to achieve balanced charge injection and improved light emitting efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the organic layer are assigned different material compositions and properties. For example, the hole injection layer uses materials optimized for hole injection, while the electron transport layer uses materials optimized for electron transport, creating local optimization throughout the structure.

Inventive Principle:
Principle #3Local quality

2Reliability

If conventional organic layer structure is used, then manufacturing process is simple, but charge recombination balance is poor leading to reduced lifespan

Engineering Contradiction:
Improvedevice lifespanVSAvoidlayer configuration
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The organic layer is divided into specialized sub-layers with distinct functions. This segmentation allows each layer to be optimized for its specific role in charge transport and recombination, improving overall device reliability and lifespan through balanced charge management.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite organic layer structures combining multiple materials with complementary properties. Each material is selected for its specific contribution to charge injection, transport, or recombination, creating a composite system that achieves superior balance and reliability.

Inventive Principle:
Principle #40Composite materials

3Productivity

If imbalanced charge injection is present, then device structure remains simple, but light emitting efficiency and lifespan are reduced

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoidcharge injection balance
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

Different sub-layers are designed with locally optimized properties: the hole injection layer is optimized for hole injection efficiency, the electron transport layer for electron mobility, and the emission layer for balanced recombination. This local optimization throughout the structure achieves global charge balance and improved light emitting efficiency.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes various parameters including material selection, layer thickness, and doping concentrations in each sub-layer to achieve balanced charge injection. By carefully adjusting these parameters, the system achieves stable and efficient charge management.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances light emitting efficiency and extends the lifespan of OLED displays by ensuring balanced charge injection and recombination, thereby stabilizing the organic light emitting diode performance.

Implementation Method 1

the holes are injected into the emission layer through the layer helping injection or transferring of the holes from the pixel electrode, and the electrons are injected into the emission layer through the layer helping injection or transferring of the electrons from the common electrode. The holes and the electrons injected into the emission layer are recombined in the emission layer to generate an exciton

Methodology Applied
Scientific EffectCharge injection and recombination:

Implementation Method 2

light is emitted while the exciton is transferred from an excited state to a ground state. In this case, light is emitted by the generated energy

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9997720B2Organic light emitting diode display
Publication Date: 2018.06.12 SAMSUNG DISPLAY CO LTD
  • US9997720B2 patent drawing
  • US9997720B2 patent drawing

AI summary

An organic light emitting display element according to an example embodiment includes: a first electrode, an emission layer positioned on the first electrode, and a second electrode positioned on the emission layer, in which the emission layer includes at least one of the compounds represented by the following Chemical Formulas 1 to 3.