Organic Light-Emitting Device Charge Transport Segmentation

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving high efficiency and long lifespan due to limitations in hole and electron transport capabilities within a single compound, leading to reduced durability and performance.

Innovation Solution

Incorporating a first compound with hole transporting capability and a second compound with electron transporting capability in the organic layer, separated within the emission layer and electron transport region, to enhance the recombination of holes and electrons and improve device durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single compound is used in the organic layer, then device structure is simple, but hole and electron transport capabilities are insufficient leading to reduced efficiency and lifespan

Engineering Contradiction:
Improvedevice lifespanVSAvoidorganic layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The organic layer is segmented into multiple functional regions: a hole transport region containing a first compound with hole transporting capability, and an electron transport region containing a second compound with electron transporting capability. This segmentation allows each compound to specialize in its respective charge carrier transport function, improving overall device efficiency and lifespan while maintaining reasonable structural organization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different compounds are assigned to different local regions of the organic layer based on their specific transport capabilities. The first compound with hole transporting capability is positioned in the hole transport region, while the second compound with electron transporting capability is positioned in the electron transport region. This local quality assignment optimizes charge carrier transport in each specific area, resolving the contradiction between simplicity and performance.

Inventive Principle:
Principle #3Local quality

2Productivity

If hole and electron transport capabilities are combined in one compound, then device structure is simplified, but transport efficiency and recombination performance deteriorate

Engineering Contradiction:
Improvecharge carrier recombination efficiencyVSAvoidcompound composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The organic layer is divided into distinct hole transport and electron transport regions, each containing compounds optimized for their specific function. This segmentation enables high-efficiency charge carrier transport and recombination by allowing each compound to specialize in its respective charge carrier type, directly improving productivity without requiring overly complex multi-compound systems.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The organic layer employs a composite structure combining different organic compounds with complementary transport properties. The first compound provides hole transporting capability while the second compound provides electron transporting capability, creating a synergistic composite material system that achieves superior recombination efficiency compared to single-compound approaches.

Inventive Principle:
Principle #40Composite materials

3Reliability

If multiple compounds are used in the organic layer, then transport capabilities are enhanced, but manufacturing complexity increases

Engineering Contradiction:
Improvecharge carrier transport capabilityVSAvoidorganic layer fabrication
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The organic layer is segmented into functional regions that can be fabricated using established multi-layer deposition techniques. Each region contains a specific compound optimized for its function, allowing for systematic manufacturing while achieving superior transport capabilities. This segmentation approach balances manufacturing feasibility with enhanced reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each compound in the organic layer is designed with multi-functionality, providing both transport capability and structural stability. The first compound serves as both the hole transport medium and structural component of the hole transport region, while the second compound similarly serves dual functions in the electron transport region. This universality reduces the need for additional auxiliary materials, simplifying manufacturing despite the use of multiple compounds.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the lifespan and efficiency of the organic light-emitting device by optimizing the movement and recombination of charge carriers, leading to enhanced emission characteristics and reduced driving voltage.

Implementation Method 1

Holes provided from the first electrode may move toward the emission layer through the hole transport region

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 2

electrons provided from the second electrode may move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

Carriers, such as holes and electrons, may be recombined in the emission layer to produce excitons

Methodology Applied
Scientific EffectCarrier recombination:

Implementation Method 4

These excitons may change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9666807B2Organic light emitting device
Publication Date: 2017.05.30 SAMSUNG DISPLAY CO LTD
  • US9666807B2 patent drawing
  • US9666807B2 patent drawing
  • US9666807B2 patent drawing

AI summary

An organic light-emitting device including a first electrode; a second electrode opposite to the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a first compound represented by the following Formula 1 and a second compound represented by the following Formula 2: