Organic Light-Emitting Device Host Material Balance

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving balanced electron and hole transport, leading to inefficiencies and reduced lifespan due to uneven emission region distribution within the emission layer, particularly when using a single host material.

Innovation Solution

Incorporating a first host and a second host with distinct substituent characteristics in the emission layer, where the second host includes a hole transporting group and the first host includes an electron transporting group, to balance electron and hole transport and prevent weighting towards specific layers, thereby improving efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single host material is used in the emission layer, then the device structure is simple, but electron and hole transport becomes unbalanced leading to reduced efficiency and lifespan

Engineering Contradiction:
Improveemission layer structureVSAvoiddevice lifespan
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The emission layer uses a composite host system comprising two different host materials with complementary properties: one host facilitates electron transport while the other facilitates hole transport. This composite approach balances charge carrier transport, prevents accumulation in specific regions, and extends device lifespan without significantly increasing structural complexity.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If a single host material is used in the emission layer, then the manufacturing process is simple, but emission region distribution becomes uneven reducing device efficiency

Engineering Contradiction:
Improveemission layer fabricationVSAvoiddevice efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

Different regions of the emission layer are designed with locally optimized properties by incorporating hosts with specific transport characteristics in different proportions or configurations. This ensures uniform emission distribution and balanced charge transport throughout the device while maintaining compatibility with standard manufacturing processes.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If host materials with identical properties are used, then the material selection is simple, but transport balance cannot be achieved leading to weighted layer formation

Engineering Contradiction:
Improvematerial selection flexibilityVSAvoidemission region distribution
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The invention changes key parameters of the host materials, specifically their charge transport characteristics. By selecting hosts with different electron mobility and hole mobility values, the system achieves balanced charge transport. The materials are chosen based on specific parameter ranges that prevent weighting effects and ensure stable, uniform emission layer composition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the efficiency and extends the lifespan of organic light-emitting devices by ensuring balanced electron and hole transport and uniform emission distribution, improving the overall performance and longevity.

Implementation Method 1

Holes from the anode may move toward the emission layer through the hole transport region, and electrons from the cathode may move toward the emission layer through the electron transport region. Carriers (e.g., the holes and the electrons), are recombined in the emission layer to produce excitons. When excitons change from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectCarrier recombination: Electroluminescence

Data Source

PatentUS9972789B2Organic light-emitting device
Publication Date: 2018.05.15 SAMSUNG DISPLAY CO LTD
  • US9972789B2 patent drawing
  • US9972789B2 patent drawing
  • US9972789B2 patent drawing

AI summary

An organic light-emitting device includes a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, where the emission layer includes a first host represented by Formula 1 and a second host represented by Formula 2:The organic light-emitting device may have high efficiency and long lifespan.