OLED Hybrid Connecting Layer for Balanced Carrier Transport

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Solution Overview

Problem

The hybrid connecting layer in OLED devices formed through alternating solution and vacuum thermal evaporation processes struggles to balance carrier transport, leading to unbalanced sub-pixel colors and reduced efficiency and lifetime.

Innovation Solution

Incorporating a hybrid connecting layer formed by a first host material with higher hole mobility and a second host material with higher electron mobility, disposed between functional layers formed through different processes, ensuring balanced carrier transport and improved interface properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a hybrid connecting layer is added to improve efficiency and lifetime of vacuum thermal evaporation formed layers, then efficiency and lifetime are improved, but carrier transport balance deteriorates causing color imbalance in sub-pixels

Engineering Contradiction:
ImproveOLED lifetimeVSAvoidcarrier transport balance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by creating different regions within the hybrid connecting layer with distinct material compositions. The layer includes a first region with materials optimized for hole transport and a second region with materials optimized for electron transport, allowing each region to perform its specific function while maintaining overall carrier balance

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining multiple organic compounds with different transport characteristics in the hybrid connecting layer. This includes mixing materials with high hole mobility with materials with high electron mobility to create a balanced interface that transports both carriers effectively

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If different materials are used at two sides of an interface for solution and vacuum thermal evaporation processes, then process compatibility is improved, but interface properties deteriorate affecting light emitting layer functions

Engineering Contradiction:
Improveprocess compatibilityVSAvoidinterface properties
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent introduces the hybrid connecting layer as an intermediary between the solution process formed layers and vacuum thermal evaporation process formed layers. This intermediate layer acts as a buffer that is compatible with both processes while ensuring proper interface properties for carrier transport

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies parameter changes by carefully selecting and adjusting material properties such as HOMO and LUMO energy levels, mobility ratios, and triplet energy values in the hybrid connecting layer to optimize both process compatibility and interface performance

Inventive Principle:
Principle #35Parameter changes

3Productivity

If a hybrid connecting layer is used to transport both electrons and holes, then carrier transport capability is improved, but material selection difficulty increases making it hard to balance carriers

Engineering Contradiction:
Improvecarrier transport capabilityVSAvoidmaterial selection complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the hybrid connecting layer into distinct functional regions - a first region for hole transport and a second region for electron transport. This segmentation simplifies material selection by allowing independent optimization of each region rather than requiring a single material to perform both functions

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the OLED's efficiency, extends its lifetime, and reduces operating voltage by effectively managing carrier transport across sub-pixels, preventing color imbalance.

Implementation Method 1

the first host material has a hole mobility greater than its electron mobility

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 2

the second host material has an electron mobility greater than its hole mobility

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

a vacuum thermal evaporation (VTE) process

Methodology Applied
Scientific EffectVacuum thermal evaporation: Evaporation

Data Source

PatentUS9412976B2Organic light emitting diode device and method for manufacturing the same, display device and electronic product
Publication Date: 2016.08.09 BOE TECHNOLOGY GROUP CO LTD
  • US9412976B2 patent drawing
  • US9412976B2 patent drawing
  • US9412976B2 patent drawing

AI summary

The OLED device according to this disclosure at least includes a first electrode, a second electrode and an organic functional layer disposed between the first electrode and the second electrode. The organic functional layer at least includes a first part functional layer formed through a first process, a second part functional layer formed through a second process, and a hybrid connecting layer disposed between the first part functional layer and the second part functional layer. The hybrid connecting layer is formed by using at least a first host material and a second host material. The first host material has a hole mobility greater than its electron mobility, and the second host material has an electron mobility greater than its hole mobility.