Maskless OLED Structuring via Repellent Layer

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Solution Overview

Problem

The existing methods for manufacturing structured organic electroluminescent light-emitting devices (OLEDs) require multiple shadow masks, which are expensive and limit the ability to fully enclose non-emitting areas, leading to inefficiencies in the manufacturing process and potential material deposition issues.

Innovation Solution

A maskless structuring method using a stack modification layer, such as perfluorinated vacuum grease or oil, is applied to create non-emitting areas within the light-emitting areas of OLEDs, allowing for the deposition of organic and conductive layers without the need for shadow masks, enabling the use of well-proven materials and maintaining reliable deposition processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If shadow masks are used to structure the functional layer stack, then the manufacturing process can be performed inline with sequential layer deposition, but the cost increases due to the need for multiple masks and the ability to fully enclose non-emitting areas is limited

Engineering Contradiction:
Improveinline processing capabilityVSAvoidnumber of masks required
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The invention extracts and removes the shadow mask component from the manufacturing process entirely. Instead of using physical masks to define patterns, the method applies a repellent layer directly to specific areas of the substrate where material deposition should be prevented. This eliminates the need for multiple masks while maintaining inline processing capability, as the repellent layer is applied before sequential layer deposition begins.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces a repellent layer as an intermediary substance between the substrate and the evaporated materials. This repellent layer acts as a mediator that prevents material adhesion in specific areas without requiring physical obstruction. The repellent layer can be applied selectively to define patterns and fully enclose non-emitting areas, solving the limitation of shadow masks while maintaining process efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If shadow masks are used to define non-emitting areas, then the pattern can be controlled, but the non-emitting areas cannot be fully enclosed due to the need for connection to the mask frame

Engineering Contradiction:
Improvepattern definition accuracyVSAvoidenclosure completeness
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The invention removes the mask frame structure entirely, replacing it with a repellent layer that can be applied directly to the substrate in any desired pattern. This allows non-emitting areas to be fully enclosed without requiring connections to a mask frame, enabling complete pattern definition including isolated islands and complex geometries that shadow masks cannot achieve.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention applies the repellent layer with local quality, meaning different areas of the substrate receive different treatments. The repellent layer is applied only to specific regions where non-emitting areas should be formed, allowing precise control over pattern definition while enabling complete enclosure of non-emitting areas. This local application method overcomes the global constraint of shadow mask frames.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If a large number of shadow masks are used for varying patterns, then different OLED designs can be manufactured, but the manufacturing cost increases significantly

Engineering Contradiction:
Improvepattern variation capabilityVSAvoidmask inventory requirements
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The invention makes the repellent layer application process universal, where a single application method can create any desired pattern by varying only the areas where the repellent layer is applied. Unlike shadow masks that require different physical masks for different patterns, the repellent layer method uses the same process step with different application locations to achieve pattern variation, eliminating the need for a large mask inventory while maintaining design flexibility.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention changes the parameter being controlled from mask selection to repellent layer application location and area. Instead of selecting different masks from an inventory, the process varies the spatial parameters of repellent layer application to achieve different patterns. This parameter change approach maintains adaptability for different OLED designs while dramatically reducing device complexity and inventory requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for easy, flexible, and reliable creation of OLEDs with non-emitting areas within light-emitting areas, fully enclosing patterns that were previously unattainable with shadow-mask techniques, reducing manufacturing costs and improving the structural integrity of OLEDs.

Implementation Method 1

The stack modification layer being a layer that comprises a perfluorinated vacuum grease or a perfluorinated vacuum pump oil... the first areas above the stack modification layer remain free of the conductive metal without masking these first areas

Methodology Applied
Scientific EffectNon-stick property:

Data Source

PatentEP2774180B1Structuring of oleds
Publication Date: 2022.01.12 PHILIPS GMBH
  • EP2774180B1 patent drawingFigure 1~2
  • EP2774180B1 patent drawingFigure 3~4
  • EP2774180B1 patent drawingFigure 5

AI summary

The invention relates to a method for manufacturing structured organic electroluminescent light-emitting devices (OLEDs) comprising light-emitting and non- emitting areas and to OLEDs manufactured according to this method comprising the steps of: Providing (P) a substrate (2) covered at least locally with at least one conductive layer as the first electrode (3); Depositing (D-SML) a stack modification layer (4) locally on top of the first electrode (3) to establish first areas (31) covered with the stack modification layer (4) and non-covered second areas (32) adjacent to the first areas (31) forming the desired structured pattern; - Depositing (D-OLS) the organic layer stack (5) comprising at least one organic light-emitting layer (51) on top of the first electrode (3) locally coated with the stack modification layer (4) providing an organic layer stack (5) being separated from the first electrode (3) by the stack modification layer (4) in between the organic layer stack (5) and the first electrode (3) in the first areas (31) and being in direct electrical contract to the first electrode (3) in the second areas (32); and Depositing (D-SE) a conductive metal layer as the second electrode (6) on top of the organic layer stack (5) to finish a functional layer stack (7), wherein the first areas (31) above the stack modification layer (4) remain free of the conductive metal without masking these first areas (31); - Providing an easy, variable and reliable method of a maskless structuring of the functional layer stack of OLED enabling to maintain the same the same deposition processes for the functional layer stack as applied during mask processing.