OLED Patterning via Silicon Nitride Shadow Masks

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Solution Overview

Problem

Current methods for patterning organic light-emitting diode (OLED) microdisplays face challenges in achieving high resolution due to the sensitivity of organics to photoresist chemistry and the limitations of metal shadow masks, which restrict sub-pixel sizes to over 10 μm and result in reduced light output from color filters.

Innovation Solution

Direct patterning of OLED layers using stencil lithography with shadow masks featuring nm-scale features, where a free-standing silicon nitride membrane acts as an etch barrier and deposition mask, allowing for precise and accurate deposition of color emitters with dimensions less than 10 microns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If metal shadow masks are used for patterning OLED layers, then color emitter layers can be formed, but the resolution is limited and sub-pixel sizes cannot be reduced below 10 μm

Engineering Contradiction:
Improvepattern resolutionVSAvoidsub-pixel size
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The patent replaces the mechanical metal shadow mask system with a photoresist-based photolithography system. This substitution enables much finer pattern resolution because photolithography can achieve sub-micron feature sizes, whereas metal shadow masks are mechanically limited to resolutions above 10 μm. The photoresist layer with its fine grain structure allows for precise pattern definition that mechanical masks cannot achieve.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental patterning parameter from mechanical aperture size (in metal masks) to optical wavelength and photoresist grain size. By using optical methods with wavelengths in the visible or UV range and fine-grain photoresist materials, the minimum feature size is reduced from tens of micrometers to sub-micron dimensions, enabling higher resolution OLED displays.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If color filters are used to create full color OLED displays, then color emission is achieved, but light output is reduced by approximately 80%

Engineering Contradiction:
Improvecolor display capabilityVSAvoidlight output
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent applies color-emitting materials directly to specific sub-pixel regions during the OLED fabrication process, before the devices are assembled and operated. By pre-defining the spatial distribution of red, green, and blue emitting materials in the organic layers, the system eliminates the need for post-fabrication color filters that would block light. The color information is built into the structure itself, allowing all generated light to contribute to the display output.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent removes the color filter component entirely from the display structure. Instead of generating white light and filtering it to produce colors, the system directly generates colored light through spatially selective emission from different organic materials. This extraction of the filtering step eliminates the 80% light loss that would otherwise occur in the color filter layer.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If photoresist processing is used for patterning, then high resolution patterns can be achieved, but organic materials are damaged due to sensitivity to photoresist chemistry

Engineering Contradiction:
Improvepattern resolutionVSAvoidorganic material sensitivity
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent introduces an inorganic buffer layer (such as silicon nitride or silicon oxide) as an intermediary between the photoresist patterning process and the sensitive organic OLED materials. This buffer layer serves as a protective barrier that is chemically resistant to photoresist solvents and etchants, allowing standard photolithography chemistry to be used without damaging the underlying organics. The buffer layer can be selectively removed or is sufficiently robust to withstand the processing conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies a protective inorganic layer to the substrate before depositing the organic materials and performing photoresist processing. This beforehand cushioning protects the vulnerable organic layers from harmful photoresist chemicals during patterning operations. The protective layer is designed to withstand the harsh chemistry of photoresist development and etching processes, shielding the organics from degradation.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the fabrication of high-efficiency, high-resolution OLED microdisplays with precise color emitter deposition, overcoming the resolution limitations of conventional methods and minimizing light loss, thereby improving pixel density and display performance.

Implementation Method 1

Conventional patterning using lithography is not possible with organics due to the sensitivity of the organics to photoresist and chemistries, which is required for photoresist processing. There are few methods to pattern organics other than photoresist such as metal shadow mask

Methodology Applied
Scientific EffectShadow masking: Shadow

Implementation Method 2

A thin film, such as silicon nitride, is deposited on both sides of the substrate using chemical vapor deposition (CVD). This silicon nitride layer may function as an etch barrier on one side and a free-standing membrane on the other side.

Methodology Applied
Scientific EffectEtch barrier:

Implementation Method 3

A thin film, such as silicon nitride, is deposited on both sides of the substrate using chemical vapor deposition (CVD)

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS9385323B2Patterning of OLED materials
Publication Date: 2016.07.05 EMAGIN CORP
  • US9385323B2 patent drawing
  • US9385323B2 patent drawing
  • US9385323B2 patent drawing

AI summary

A method of making a patterned OLED layer or layers. The method uses a shadow mask having, for example, a free-standing silicon nitride membrane to pattern color emitter material with a feature size of less than 10 microns. The methods can be used, for example, in the manufacture of OLED microdisplays.