OLED Flexible Substrate Silicon Nitride Barrier Adhesion

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Solution Overview

Problem

Organic light-emitting diode (OLED) displays with flexible substrates face challenges in maintaining low water vapor transmission rates and high adhesive strength, leading to potential damage from moisture and oxygen penetration, which can reduce the lifespan of the OLED and cause detachment defects during manufacturing.

Innovation Solution

The OLED display incorporates a flexible substrate with alternating layers of plastic and silicon nitride barrier layers, where the density and refractive index of silicon nitride in the barrier layers vary to enhance water vapor barrier properties and adhesive strength, and an intermediate layer is added between the barrier and plastic layers to improve adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a flexible substrate with plastic layers is used in OLED display, then flexibility and ease of manufacture are improved, but water vapor transmission rate increases and adhesive strength decreases

Engineering Contradiction:
ImproveflexibilityVSAvoidwater vapor transmission rate
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs a composite structure consisting of alternating organic plastic layers and inorganic barrier layers (silicon nitride). This composite material approach combines the flexibility and ease of manufacture of organic materials with the low water vapor transmission properties of inorganic materials, resolving the contradiction between flexibility and moisture barrier performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The substrate is segmented into multiple thin layers (plastic layer 1, barrier layer 1, plastic layer 2, barrier layer 2, etc.) rather than using a single thick plastic layer. This segmentation creates multiple interfaces that collectively provide both flexibility and effective moisture barrier properties, as each layer contributes specific functional characteristics.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If a flexible substrate with plastic layers is used in OLED display, then flexibility and ease of manufacture are improved, but adhesive strength decreases

Engineering Contradiction:
ImproveflexibilityVSAvoidadhesive strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The alternating organic-inorganic layered structure creates a composite material system where the different materials complement each other's properties. The plastic layers provide flexibility while the barrier layers provide adhesion, resolving the contradiction between ease of manufacture and adhesive strength.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different layers are assigned different local qualities: plastic layers are optimized for flexibility and organic-inorganic interface compatibility, while barrier layers are optimized for adhesion and moisture barrier properties. This local differentiation allows each layer to excel at its specific function without compromising the overall structure.

Inventive Principle:
Principle #3Local quality

3Reliability

If barrier layers are added to reduce water vapor transmission, then moisture protection is improved, but device complexity increases

Engineering Contradiction:
Improvewater vapor transmission rateVSAvoidlayer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The moisture barrier function is segmented across multiple thin alternating layers rather than requiring a single complex thick barrier. This segmentation achieves effective moisture protection through the cumulative effect of multiple interfaces while keeping each individual layer simple and manageable.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses thin film structures for both the plastic and barrier layers, creating a flexible multi-layered shell structure. This approach provides effective moisture barrier properties through the thin-film stack while maintaining flexibility and avoiding the complexity of thick rigid barriers.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration increases the average water vapor transmission path, reduces detachment defects, and improves the characteristics of the thin-film transistor (TFT) by maintaining a low water vapor transmission rate while enhancing adhesive strength between the barrier and plastic layers, thus extending the OLED's lifespan and manufacturing reliability.

Implementation Method 1

a flexible substrate that has a low water vapor transmission rate... The first barrier layer may include silicon nitride... The silicon nitride may be present within the first barrier layer at a density of equal to or more than 2.2 g/cm3 and less than or equal to 2.4 g/cm3

Methodology Applied
Scientific EffectPermeation barrier: Permeation

Implementation Method 2

a first intermediate layer each positioned between the first and second plastic layers... enhancing adhesive strength... improves the characteristics of the thin-film transistor (TFT) by maintaining a low water vapor transmission rate while enhancing adhesive strength between the barrier and plastic layers

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS9178178B2Organic light-emitting diode display having improved adhesion and damage resistance characteristics, an electronic device including the same, and method of manufacturing the organic light-emitting diode display
Publication Date: 2015.11.03 SAMSUNG DISPLAY CO LTD
  • US9178178B2 patent drawing
  • US9178178B2 patent drawing
  • US9178178B2 patent drawing

AI summary

Provided is an organic light-emitting diode (OLED) display including: first and second plastic layers; a first barrier layer and a first intermediate layer each positioned between the first and second plastic layers; and an OLED layer formed on the second plastic layer. The first barrier layer comprises silicon nitride.