Organic EL Electron Transport Composition for Low Voltage

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in achieving high performance with multiple materials used in combination, often resulting in deteriorated performance or failure to meet expected improvements in driving voltage and efficiency.

Innovation Solution

A composition comprising specific compounds represented by formulas (1) and (2), which are different, are used to enhance the performance of organic electroluminescence devices by forming a low-driving-voltage and high-efficiency organic EL device, with the compounds being used in the electron-transporting region between the emitting layer and the cathode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If two or more materials are used in combination in an organic EL device, then device performance improvement is attempted, but the advantages of respective materials are not necessarily maintained and performance may be deteriorated

Engineering Contradiction:
Improvedevice performanceVSAvoidperformance deterioration
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical structure parameters of the compounds by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and controlling nitrogen atom positions to achieve optimal electron transport properties while maintaining material advantages in combinations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining compounds with specific heterocyclic structures (formulas 1 and 2) that contain multiple heterocyclic rings and nitrogen atoms, creating synergistic effects that improve device performance while avoiding the pitfalls of random material combinations

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional materials are used in the electron-transporting region, then device fabrication is straightforward, but driving voltage remains high and efficiency is limited

Engineering Contradiction:
Improvefabrication simplicityVSAvoiddriving voltage
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent changes the electronic parameters of the electron-transporting materials by incorporating heterocyclic groups with specific nitrogen atom configurations, which modify the LUMO energy levels and electron mobility to reduce driving voltage while maintaining ease of fabrication through solution processing

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional materials are used in the electron-transporting region, then device structure is simple, but efficiency is not sufficiently improved

Engineering Contradiction:
Improvestructure simplicityVSAvoiddevice efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The patent changes the molecular parameters of the compounds by introducing heterocyclic groups and controlling nitrogen atom positions to enhance electron transport efficiency while maintaining relatively simple device structures with standard layer configurations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials with specific heterocyclic compound combinations that achieve high efficiency through synergistic electron transport mechanisms while keeping the overall device structure simple and compatible with conventional fabrication processes

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds in the organic EL device achieves a significant reduction in driving voltage and improvement in efficiency, as demonstrated by the examples provided, where specific combinations and ratios of the compounds in the electron-transporting layers enhance the device's performance.

Implementation Method 1

When voltage is applied to an organic electroluminescence device, holes and electrons are injected into an emitting layer from an anode and a cathode, respectively. Then, thus injected holes and electrons are recombined in the emitting layer, and excitons are formed therein.

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

an organic electroluminescence device (hereinafter, referred to as an organic EL device), holes and electrons are injected into an emitting layer from an anode and a cathode, respectively

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220344594A1Composition, powder, organic electroluminescence device, method of fabricating organic electroluminescence device, and electronic apparatus
Publication Date: 2022.10.27 IDEMITSU KOSAN CO LTD
  • US20220344594A1 patent drawing
  • US20220344594A1 patent drawing
  • US20220344594A1 patent drawing

AI summary

A composition comprising a compound represented by the following formula (1) and a compound represented by the following formula (2), provided that the compound represented by the formula (1) and the compound represented by the formula (2) are different compounds: