Non-destructive Thickness Measurement of Organic Electronic Layers

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Solution Overview

Problem

There is no non-destructive method to measure the thickness of the electron injection layer in organic electronic devices, which is critical for their performance and is prone to degradation when exposed to air, making standard measurement tools ineffective.

Innovation Solution

A method involving the generation of baseline reflectance profiles from devices with known layer thicknesses, comparison of the device's reflectance profile to these baselines, and use of data analysis software to determine the layer thickness in a non-destructive and near real-time manner.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If standard physical measurement tools (step height profilers) are used to measure the electron injection layer thickness, then measurement capability is provided, but the layer must be exposed to air which causes degradation

Engineering Contradiction:
Improvelayer thickness measurementVSAvoidlayer stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent replaces mechanical measurement tools (step height profilers requiring physical contact and air exposure) with optical measurement methods (reflectance and transmission spectroscopy). This allows non-destructive thickness measurement through the encapsulation structure without exposing the sensitive electron injection layer to air, thereby maintaining both measurement capability and layer stability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses optical signals (light) as an intermediary to measure layer thickness indirectly through reflectance and transmission profiles. This intermediary approach enables measurement through the encapsulation structure without direct physical contact with the electron injection layer, avoiding air exposure while obtaining accurate thickness data.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If the electron injection layer is encapsulated immediately to protect it from degradation, then layer stability is maintained, but non-destructive measurement becomes impossible

Engineering Contradiction:
Improvelayer stabilityVSAvoidlayer thickness measurement
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent replaces mechanical measurement tools that require physical access to the layer with optical measurement methods. Reflectance and transmission spectroscopy can penetrate the encapsulation structure to obtain thickness information without compromising the sealed environment, thus maintaining both protection and measurement capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent creates optical signatures (reflectance and transmission profiles) that serve as copies or representations of the layer thickness information. By comparing these optical copies against reference data or using computational analysis, the actual thickness is determined without physically accessing or exposing the encapsulated layer.

Inventive Principle:
Principle #26Copying

3Manufacturing precision

If the electron injection layer thickness is made extremely thin to optimize device performance, then device performance is improved, but measurement difficulty increases

Engineering Contradiction:
Improvelayer thickness optimizationVSAvoidlayer thickness measurement
Core Design Contradiction:
Manufacturing precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces inadequate mechanical measurement methods with sensitive optical spectroscopy techniques. Reflectance and transmission measurements provide precise thickness information for ultra-thin layers through their characteristic optical interference patterns, enabling accurate measurement of layers too thin for conventional mechanical tools.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent exploits changes in optical parameters (reflectance and transmission characteristics) as a function of layer thickness. By analyzing how these optical parameters vary with thickness through interference patterns and absorption features, the method achieves high precision measurement of extremely thin layers that are difficult to measure by other means.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate, non-destructive measurement of the electron injection layer thickness in organic electronic devices, ensuring quality control and performance consistency without damaging the devices.

Implementation Method 1

A method is provided for measuring a layer of a device. The method includes generating a set of baseline reflectance profiles from a corresponding set of baseline devices... generating a reflectance profile from the device and comparing the generated reflectance profile

Methodology Applied
Scientific EffectReflectance: Reflection

Data Source

PatentUS7586622B1Measuring thickness of a device layer using reflectance and transmission profiles of baseline devices
Publication Date: 2009.09.08 LG CHEM LTD
  • US7586622B1 patent drawing
  • US7586622B1 patent drawing
  • US7586622B1 patent drawing

AI summary

A method for measuring a layer of a device is provided. In an embodiment, a set of baseline reflectance profiles may be generated from a corresponding set of baseline devices. Each of the baseline devices may include a layer with a known thickness. A reflectance profile may also be generated from the device, which may include a layer with an unknown thickness. The reflectance profile generated from the device may then be compared to the set of reflectance profiles generated from the set of the baseline devices to determine the thickness of the layer of the device.