Organic Electronic Substrate with Particle-Containing Layer for Light Extraction

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Solution Overview

Problem

In organic electronic devices (OEDs), such as OLEDs, a significant amount of light is trapped due to the refractive index mismatch between the organic layer and the substrate, leading to low light extraction efficiency.

Innovation Solution

A substrate with a particle-containing layer comprising first and second particles of different refractive indices and sizes, along with a binder, is used to enhance light scattering and extraction, while maintaining thermal and chemical resistance, and an overcoat layer is applied to optimize refractive index and planarization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a conventional substrate structure with uniform refractive index is used, then the device structure is simple and easy to manufacture, but light extraction efficiency is low due to total internal reflection at interfaces

Engineering Contradiction:
Improvestructural simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The substrate is constructed as a composite material system consisting of a base substrate layer and a particle-containing layer. The particle-containing layer incorporates particles with refractive indices of 1.7 or higher (such as TiO2, SiO2, or ZrO2 particles) dispersed in a binder resin, creating a composite structure that combines the mechanical strength of the base substrate with the light scattering properties of the high-refractive-index particles. This composite structure effectively reduces total internal reflection and improves light extraction efficiency while maintaining manufacturing feasibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Instead of making the entire substrate uniformly complex, the invention applies the particle-containing layer only in specific regions where light extraction enhancement is needed. The particle-containing layer can be positioned adjacent to the organic light-emitting layer or distributed in specific patterns, allowing local optimization of light extraction properties without complicating the entire substrate structure. This localized approach maintains ease of manufacture while improving light extraction efficiency where it matters most.

Inventive Principle:
Principle #3Local quality

2Reliability

If particles are added to the substrate to scatter light, then light extraction efficiency is improved, but the substrate surface becomes uneven and requires additional planarization steps

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidsurface planarization requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention introduces a thin film layer (such as an adhesive layer or planarization layer) with a thickness of 1 μm or less that covers the particle-containing layer. This thin film acts as a flexible shell that smooths out the surface irregularities caused by the particles while maintaining the underlying light scattering structure. The thin film approach effectively planarizes the surface for subsequent electrode and organic layer deposition without requiring complex mechanical planarization processes, thus improving light extraction efficiency while controlling device complexity.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If high refractive index particles are incorporated into the substrate, then light scattering is enhanced, but the manufacturing precision is reduced due to surface unevenness

Engineering Contradiction:
Improvelight scattering performanceVSAvoidsurface flatness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

A thin film layer with thickness of 1 μm or less is introduced to cover the particle-containing layer, effectively smoothing the surface while preserving the light scattering function of the particles beneath. This thin film acts as a flexible shell that masks surface irregularities, enabling subsequent manufacturing steps (such as electrode deposition and organic layer formation) to proceed with high precision. The thin film approach maintains the light scattering performance of the high-refractive-index particles while restoring surface flatness to acceptable manufacturing tolerances.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The thin film layer serves as an intermediary between the particle-containing layer and the subsequent device structures. It mediates the conflict between light scattering performance and surface flatness by providing a smooth interface for subsequent manufacturing steps while allowing the particle-containing layer to maintain its light scattering function. This intermediary layer effectively decouples the two requirements, allowing high light scattering performance without compromising manufacturing precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The substrate significantly improves light extraction efficiency and reliability of OEDs by scattering trapped light and maintaining structural integrity during manufacturing processes.

Implementation Method 1

A substrate with a particle-containing layer comprising first and second particles of different refractive indices and sizes, along with a binder, is used to enhance light scattering and extraction

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

light generated in the organic emitting layer in the bottom emitting device is trapped by total internal reflection at an interface between the organic layer and the first electrode layer, or in the substrate

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Data Source

PatentEP2882006B1Substrate for organic electronic device
Publication Date: 2021.05.19 LG CHEM LTD
  • EP2882006B1 patent drawingFigure 1~2
  • EP2882006B1 patent drawingFigure 3
  • EP2882006B1 patent drawingFigure 4~5

AI summary

The present application relates to a substrate for an organic electronic diode (OED), an organic electronic system, and a lighting. In the present application, the substrate capable of forming an OED or the organic electronic system can ensure performance including light extracting efficiency and reliability is provided.