Organometallic Complex Dopant for OLED Efficiency and Lifetime

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving low driving voltage, high light-emitting efficiency, and long lifetime, particularly in the development of materials for the light emitting layer, where existing dopant materials do not consistently meet these requirements.

Innovation Solution

Incorporating an organometallic complex with a specific chemical structure, featuring a first and second metal complex connected by an aromatic ring group, which serves as a dopant in the light emitting layer, enhancing the stability and efficiency of the organic electroluminescence device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing dopant materials are used in the light emitting layer, then the device can operate, but the lifetime and light-emitting efficiency are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidlight-emitting efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent uses a composite organometallic complex containing both phosphorescent and TADF metal complexes (Ir or Pt) within the same molecular structure. This composite approach allows the material to exhibit both phosphorescence and thermally activated delayed fluorescence mechanisms, thereby improving light-emitting efficiency while maintaining long lifetime characteristics, resolving the contradiction between reliability and productivity

Inventive Principle:
Principle #40Composite materials

2Productivity

If single metal complex dopants are used, then the structure is simple, but light-emitting efficiency and lifetime are limited

Engineering Contradiction:
Improvelight-emitting efficiencyVSAvoidcomplex structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges two different metal complexes (phosphorescent Ir complex and TADF Pt complex) into a single organometallic complex molecule. This merging enables dual emission mechanisms (phosphorescence and TADF) to work together, significantly improving light-emitting efficiency without requiring separate dopant materials, thus balancing productivity improvement with acceptable structural complexity

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If conventional dopant materials are used, then manufacturing is easier, but the device cannot achieve low driving voltage and high efficiency simultaneously

Engineering Contradiction:
Improvematerial fabricationVSAvoiddriving voltage
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the dopant material by incorporating specific metal complexes (Ir or Pt) with defined ligand structures. This parameter change enables the material to achieve optimal energy levels and electron-hole recombination characteristics, allowing the device to operate at low driving voltage while maintaining high efficiency, without significantly complicating the manufacturing process

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this organometallic complex results in improved light-emitting efficiency and extended device lifetime, even under low driving voltage conditions, compared to devices using single metal complexes.

Implementation Method 1

The organic electroluminescence display device is configured to produce excitons in a light emitting layer through recombinations of holes and electrons injected from a first electrode and a second electrode and to display an image using light, which is generated when the produced excitons fall to the ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11527730B2Organic electroluminescence device and organometallic complex for organic electroluminescence device
Publication Date: 2022.12.13 SAMSUNG DISPLAY CO LTD
  • US11527730B2 patent drawing
  • US11527730B2 patent drawing
  • US11527730B2 patent drawing

AI summary

An organic electroluminescence device may include a first electrode, a second electrode opposite to the first electrode, and organic layers disposed between the first electrode and the second electrode. At least one of organic layers may include an organometallic complex including a first metal complex having a metal atom as a center atom of the first metal complex, a second metal complex having the metal atom as a center atom of the second metal complex, and an aromatic ring group connecting the first metal complex to the second metal complex.