Oxide Semiconductor TFT Plasma Treatment for Mobility

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Solution Overview

Problem

Existing methods for manufacturing thin film transistors face challenges in improving charge carrier mobility without changing the semiconductor material, particularly in achieving high mobility at lower annealing temperatures to maintain the amorphous-crystalline structure.

Innovation Solution

A method involving the formation of an amorphous oxide semiconductor layer on a base substrate, followed by plasma treatment using nitrogen or nitric oxide gas to reduce defects, and subsequent annealing at 400°C or less to form a channel layer, which enhances charge carrier mobility without altering the material composition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional annealing methods are used to improve charge carrier mobility, then mobility increases, but annealing temperature must be increased which may alter the amorphous-crystalline structure

Engineering Contradiction:
Improvecharge carrier mobilityVSAvoidannealing temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies plasma treatment to the oxide semiconductor layer before annealing to pre-reduce defects and improve material quality. This preliminary action enables subsequent annealing at lower temperatures (400-600°C) to achieve high charge carrier mobility without requiring excessive heating that would alter the amorphous-crystalline structure

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical composition parameters of the oxide semiconductor layer by introducing nitrogen or nitric oxide through plasma treatment. This compositional modification reduces defects and enables improved charge carrier mobility at lower annealing temperatures while preserving the amorphous-crystalline structure

Inventive Principle:
Principle #35Parameter changes

2Reliability

If plasma treatment is applied to reduce defects in oxide semiconductor layer, then charge carrier mobility improves, but additional process steps are required

Engineering Contradiction:
Improvecharge carrier mobilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the plasma treatment step with the existing annealing process by performing plasma treatment immediately before annealing in the same manufacturing sequence. This integration allows defect reduction and structural optimization to occur in a coordinated manner, achieving high mobility without requiring completely separate manufacturing lines

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves charge carrier mobility in thin film transistors by reducing defects through plasma treatment and annealing, while maintaining the amorphous-crystalline structure, thus enhancing the driving speed and reliability of the transistors without increasing manufacturing costs or time.

Implementation Method 1

plasma-treating the oxide semiconductor layer using a plasma generated from a nitrogen gas or a nitric oxide gas to decrease defects in the oxide semiconductor layer

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

plasma generated from a nitrogen gas or a nitric oxide gas

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

annealing the plasma-treated oxide semiconductor layer to form a channel layer from the plasma-treated oxide semiconductor layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 4

annealing is performed at a temperature of about 400° C. or less

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS9412771B2Method of manufacturing thin film transistor and method of manufacturing display substrate having the same
Publication Date: 2016.08.09 SAMSUNG DISPLAY CO LTD
  • US9412771B2 patent drawing
  • US9412771B2 patent drawing
  • US9412771B2 patent drawing

AI summary

A method of manufacturing a thin film transistor and a method of manufacturing a display substrate having the same are disclosed. In one aspect, the method of manufacturing a thin film transistor comprises forming an oxide semiconductor layer over a substrate, plasma-treating the oxide semiconductor layer with a plasma generated from a nitrogen gas or a nitric oxide gas so as to decrease defects in the oxide semiconductor layer, and annealing the plasma-treated oxide semiconductor layer to form a channel layer.