Particle Beam Etching of EUV Lithography Masks

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Solution Overview

Problem

Current methods for producing lithography masks, especially those for deep ultraviolet (DUV) and extreme ultraviolet (EUV) microlithography, face challenges in achieving high resolution and precision due to defects caused by etching processes, which can lead to unintended structure formation and reduced functionality of the masks.

Innovation Solution

A method for particle beam-induced etching of lithography masks involves providing a focused particle beam and specific gaseous components, including a reactive etching gas and a deposition gas, to control the etching process, allowing for targeted removal of defects and improved resolution by forming volatile compounds and minimizing damage to the mask.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching procedures are used to produce lithography mask structures, then manufacturing capability is achieved, but defects such as unintended structures and incomplete etching occur, reducing manufacturing precision

Engineering Contradiction:
Improveetching precisionVSAvoiddefect-free operation
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A protective layer is introduced as an intermediary between the particle beam and the lithography mask substrate. This protective layer enables controlled etching by being selectively removed in defect regions while protecting intact areas, thereby improving etching precision and eliminating defects without damaging the overall mask structure

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protective layer is applied in advance before the etching process. This preliminary action allows the mask to be prepared in a protected state, enabling subsequent selective etching operations to proceed with higher precision and reliability by preventing unintended etching in non-defect areas

Inventive Principle:
Principle #10Preliminary action

2Productivity

If high energy particle beams are used to etch lithography masks, then etching speed increases, but damage to the mask structure and unintended etching occur, worsening manufacturing precision

Engineering Contradiction:
Improveetching speedVSAvoidstructure integrity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The protective layer serves as a mediator that allows high energy particle beams to etch quickly while protecting the mask substrate from direct beam damage. The layer absorbs the harsh etching conditions, enabling fast processing without compromising structure integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protective layer converts the potentially harmful high energy particle beam into a beneficial fast etching tool. By sacrificing the protective layer in controlled manner, the high energy beam achieves rapid etching while the layer itself prevents damage to the underlying mask structure

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Manufacturing precision

If multiple etching steps are performed to achieve high resolution, then manufacturing precision improves, but process complexity and time increase, reducing productivity

Engineering Contradiction:
Improvestructure resolutionVSAvoidprocess efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

Multiple etching operations are merged into a single integrated process by using the protective layer approach. Instead of performing separate etching steps, the protective layer enables all necessary etching to be done in one coordinated operation, maintaining high resolution while improving productivity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the control and precision of the etching process, enabling the creation of smaller structures and reducing defects, thereby improving the quality and functionality of lithography masks.

Implementation Method 1

a focused particle beam is beamed onto a target position on the lithography mask; at least one first gaseous component is supplied to the target position, wherein the first gaseous component can be converted by activation into a reactive form

Methodology Applied
Scientific EffectParticle beam activation: Photoionisation

Implementation Method 2

the reactive form reacts with a material of the lithography mask to form a volatile compound

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

at least one second gaseous component is supplied to the target position in the process atmosphere, wherein the second gaseous component comprises a compound of silicon with oxygen, nitrogen and/or carbon

Methodology Applied
Scientific EffectGas deposition: Deposition (physical)

Data Source

PatentUS20230185180A1Method and apparatus for etching a lithography mask
Publication Date: 2023.06.15 CARL ZEISS SMT GMBH
  • US20230185180A1 patent drawing
  • US20230185180A1 patent drawing
  • US20230185180A1 patent drawing

AI summary

Method for the particle beam-induced etching of a lithography mask, more particularly a non-transmissive EUV lithography mask, having the steps of:a) providing the lithography mask in a process atmosphere,b) beaming a focused particle beam onto a target position on the lithography mask,c) supplying at least one first gaseous component to the target position in the process atmosphere, where the first gaseous component can be converted by activation into a reactive form, where the reactive form reacts with a material of the lithography mask to form a volatile compound, andd) supplying at least one second gaseous component to the target position in the process atmosphere, where the second gaseous component under predetermined process conditions with exposure to the particle beam forms a deposit comprising a compound of silicon with oxygen, nitrogen and/or carbon.