Patterned Metallization via Imprinting and Self-Organization

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Solution Overview

Problem

Current methods for providing patterned metallization in OLEDs and organic solar cells are expensive and complicated, requiring expensive lithographic equipment and time-consuming processes, which limits the size of uniformly lit areas due to high sheet resistance of anode and cathode materials.

Innovation Solution

A method utilizing an imprinting process to create patterned layers on substrates without the need for expensive equipment, involving a patterning means to create recesses, followed by deposition of polar molecule-containing layers that redistribute into hydrophilic areas, allowing for the formation of conducting grids and meshes for improved current spreading and shunting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If photolithography and thick film technology are used for patterned metallization, then manufacturing precision is improved, but device complexity and production cost increase

Engineering Contradiction:
Improvepatterned metallization precisionVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical photolithography system with a self-organizing chemical system. Polar molecules automatically form patterns through electrostatic interactions and capillary action during drying, eliminating the need for complex lithographic equipment and multiple fabrication steps while achieving the required pattern precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patterned metallization is achieved through self-organization of polar molecules that automatically concentrate in hydrophilic regions during the drying process. This self-service mechanism eliminates the need for external patterning equipment and complex manufacturing procedures, reducing both device complexity and production cost.

Inventive Principle:
Principle #25Self-service

2Manufacturing precision

If photolithography and expensive equipment are used, then manufacturing precision is improved, but production cost increases

Engineering Contradiction:
Improvepatterned metallization precisionVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent uses inexpensive, easily disposable materials such as polar molecule solutions and hydrophilic coating materials that can be applied through simple dip-coating or spray techniques. These low-cost materials achieve the required pattern precision without requiring expensive lithographic equipment, significantly reducing production cost while maintaining manufacturing precision.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent substitutes expensive mechanical lithography equipment with a simple chemical self-organization process. The pattern formation occurs automatically through electrostatic interactions and capillary action, eliminating the need for costly equipment while achieving the required pattern precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If conventional thin film materials are used for electrodes, then ease of manufacture is improved, but sheet resistance increases

Engineering Contradiction:
Improveelectrode fabrication easeVSAvoidsheet resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite electrode structure combining a hydrophilic substrate layer with concentrated polar molecules that form conductive pathways. This composite approach achieves low sheet resistance by utilizing the self-organizing properties of polar molecules to create efficient charge transport paths, while maintaining ease of manufacture through simple coating processes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by concentrating polar molecules specifically in hydrophilic regions of the substrate. This localized concentration creates areas of high electrical conductivity where needed, achieving low sheet resistance in specific patterns without requiring uniform thick metal deposition across the entire electrode area.

Inventive Principle:
Principle #3Local quality

4Area of stationary object

If large area OLEDs are manufactured with conventional electrodes, then area is increased, but voltage drop increases

Engineering Contradiction:
Improvelight tile areaVSAvoidvoltage drop
Core Design Contradiction:
Area of stationary objectVSLoss of energy

Solution Approach 1:

The patent implements local quality by creating patterns of hydrophilic regions that concentrate polar molecules to form conductive pathways. This localized conductivity enhancement reduces voltage drop in specific areas of large light tiles, enabling larger display areas without proportionally increasing energy loss.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the electrode into multiple hydrophilic regions separated by hydrophobic barriers. This segmentation creates a network of conductive pathways that distribute current efficiently across large areas, reducing overall voltage drop by providing multiple parallel conduction paths rather than relying on a single continuous electrode layer.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces production costs and time, enables the creation of substrates with low sheet resistance, and extends the size of uniformly lit areas by providing a low-cost, efficient way to manufacture patterned metallization for OLEDs and organic solar cells, enhancing light efficiency and reducing voltage drops.

Implementation Method 1

imprinting a patterning means into a first layer to create a pattern of recesses

Methodology Applied
Scientific EffectImprinting:

Implementation Method 2

the second layer is redistributed from the hydrophobic subarea into the recesses

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 3

the second layer is redistributed from the hydrophobic subarea into the recesses

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 4

the first layer is a sol-gel material or wherein the first layer is a polymer

Methodology Applied
Scientific EffectSol-gel process:

Implementation Method 5

at least partly reacting the sol-gel material before the step of imprinting

Methodology Applied
Scientific EffectChemical reaction:

Implementation Method 6

applying a treatment, wherein the precursors are converted to nucleation sites for deposition of electro-less metal, depositing a thin electro-less metal layer on the nucleation sites

Methodology Applied
Scientific EffectElectro-less metal deposition:

Data Source

PatentEP2165366B8A method for forming a patterned layer on a substrate
Publication Date: 2018.12.26 BEIJING XIAOMI MOBILE SOFTWARE CO LTD

AI summary

This invention relates to a method for forming a patterned layer on a substrate by means of an imprint process. According to the method a first layer is provided on the substrate, and a pattern of recesses is provided in the first layer by imprinting the layer with a patterning means. Then the first layer is cured. The curing is followed by performing a first surface treatment onto the first layer to make the surface of thereof hydrophilic, and then performing a second surface treatment onto a selected subarea of the surface of the first layer to make the. subarea hydrophobic. The subarea includes surface portions between the recesses and excludes the recesses. Finally, a conducting pattern material (41) is deposited into the recesses.