PCB Insulating Layer Resin Composition for Warpage Suppression

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Solution Overview

Problem

Conventional approaches to reduce warpage in semiconductor plastic packages by modifying the thermal expansion and rigidity of printed circuit boards have reached their limits, leading to issues with moldability, heat resistance, and reliability.

Innovation Solution

An insulating layer for printed circuit boards is developed using a resin composition comprising alkenyl-substituted nadimide, maleimide compound, cyanic acid ester compound, and an inorganic filler, with specific ratios and content levels to maintain a low difference in flexural modulus between 25°C and 250°C, enhancing moldability and heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional approaches are used to reduce thermal expansion of insulating layers, then thermal expansion is reduced, but further reduction has reached its limit and cannot achieve sufficient warpage suppression

Engineering Contradiction:
Improvewarpage suppressionVSAvoidthermal expansion reduction limit
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the fundamental parameter from thermal expansion coefficient to flexural modulus temperature dependence. By designing a resin composition where the flexural modulus difference between 25°C and 250°C is within 20%, the invention achieves warpage suppression through rigidity stability rather than thermal expansion control, overcoming the conventional limit

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite resin composition containing multiple components (cyanate resin, maleimide compound, alkenyl-substituted nadimide, and inorganic filler) to achieve the desired flexural modulus characteristics. This composite approach allows tuning of the modulus temperature dependence to meet the 20% difference requirement

Inventive Principle:
Principle #40Composite materials

2Strength

If fillers are highly incorporated into resin compositions to achieve high rigidity, then rigidity increases, but moldability deteriorates

Engineering Contradiction:
ImproverigidityVSAvoidmoldability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent changes the approach from increasing rigidity through filler content to achieving rigidity through controlled crosslinking density and flexural modulus temperature dependence. By limiting the flexural modulus difference to 20% between temperatures, the invention achieves high rigidity while maintaining moldability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite resin system with cyanate resin, maleimide compound, and inorganic filler in specific proportions. This composite formulation achieves the desired rigidity-moldability balance through synergistic interactions among components rather than simply increasing filler loading

Inventive Principle:
Principle #40Composite materials

3Strength

If inorganic fillers such as alumina are used to achieve high rigidity, then rigidity increases, but the coefficient of thermal expansion deteriorates

Engineering Contradiction:
ImproverigidityVSAvoidcoefficient of thermal expansion
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent shifts the control parameter from thermal expansion coefficient to flexural modulus temperature dependence. By focusing on maintaining flexural modulus within 20% difference between 25°C and 250°C, the invention achieves warpage suppression without being constrained by thermal expansion coefficient requirements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite resin composition with cyanate resin, maleimide compound, and inorganic filler that achieves the desired mechanical properties. This composite system provides both high rigidity and favorable thermal expansion characteristics through the synergistic combination of organic and inorganic components

Inventive Principle:
Principle #40Composite materials

4Temperature

If crosslink density is elevated to achieve high Tg, then glass transition temperature increases, but heat resistance upon moisture-absorbing deteriorates

Engineering Contradiction:
Improveglass transition temperatureVSAvoidheat resistance upon moisture-absorbing
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the target parameter from glass transition temperature to flexural modulus temperature dependence. By controlling the flexural modulus difference to within 20% between 25°C and 250°C, the invention achieves high-temperature performance without relying solely on elevated Tg, thereby maintaining heat resistance after moisture absorption

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite resin system where cyanate resin and maleimide compound form a crosslinked network with controlled density. The inclusion of inorganic filler and specific compound ratios (5-15 parts cyanic acid ester compound, β/α ratio of 0.9-4.3) achieves the desired flexural modulus characteristics while maintaining moisture resistance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses warpage in semiconductor plastic packages while maintaining excellent elastic modulus and heat resistance, improving production yields and reliability.

Implementation Method 1

the difference in the coefficient of thermal expansion between a semiconductor device and a printed circuit board for semiconductor plastic packages causes the undesired warpage of semiconductor plastic packages

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentEP3094162B1Insulating layer for printed wire board, and printed wire board
Publication Date: 2023.08.09 MITSUBISHI GAS CHEM CO INC
  • EP3094162B1 patent drawing
  • EP3094162B1 patent drawing
  • EP3094162B1 patent drawing

AI summary

The present invention provides an insulating layer for printed circuit boards having a difference of within 20% between the flexural modulus at 25°C and the flexural modulus under heat at 250°C.