Phase Change Memory Contact Interface with Intermediate Layer

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional phase change memory devices experience increased contact resistance when silicon (Si) is directly joined to the phase change material, leading to higher costs and complex structures, as Si forms a Schottky junction with metallic materials, which increases electric resistance.

Innovation Solution

The introduction of an intermediate layer containing constituent elements of the phase change material, such as Si-Sb, Si-Te, or Si-Sn, between the Si and the phase change material to reduce contact resistance and simplify the device structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If Si is directly joined to the phase change material, then the device structure is simplified, but contact resistance increases due to Schottky junction formation

Engineering Contradiction:
Improvedevice structureVSAvoidcontact resistance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

An intermediate layer containing constituent elements of the phase change material (such as Si-Sb, Si-Te, or Si-Sn) is introduced between the Si and the phase change material. This intermediate layer acts as a mediator that reduces contact resistance while maintaining structural simplicity, preventing the formation of high-resistance Schottky junctions between Si and metallic phase change materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Power

If metallic materials are used for electrodes adjacent to phase change film, then electrical conduction is achieved through free-electron conduction, but contact resistance increases when joined with Si

Engineering Contradiction:
Improveelectrical conductionVSAvoidcontact resistance
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The intermediate layer containing phase change material constituents serves as a mediator between the metallic phase change material and Si electrode. This layer enables effective electrical conduction by preventing the formation of high-resistance Schottky junctions, while maintaining the free-electron conduction properties of the metallic materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The intermediate layer is formed as a composite material containing both Si and constituent elements of the phase change material (such as Sb, Te, or Sn). This composite structure combines the advantages of Si-based materials with phase change material constituents to achieve low contact resistance while maintaining electrical conduction.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The intermediate layer significantly decreases contact resistance, enhances the reliability of phase change memory operations by allowing reversible resistance switching, and reduces production costs by simplifying the device structure and materials used.

Implementation Method 1

the joining of the Si to the phase change material increases contact resistance. This is because a Schottky junction is formed when a material bonded to Si is a metallic material

Methodology Applied
Scientific EffectSchottky junction: Conduction (electrical)

Implementation Method 2

Data is rewritten such that the state of the phase change film is changed between the amorphous and crystalline states by Joule heat generated by the current

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 3

a phase change film is sandwiched between a pair of metal electrodes... the state of the phase change film is changed to the amorphous state of high resistance... the state of the phase change film is changed to the crystalline state of low resistance

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS8658998B2Semiconductor storage device
Publication Date: 2014.02.25 HITACHI LTD
  • US8658998B2 patent drawing
  • US8658998B2 patent drawing
  • US8658998B2 patent drawing

AI summary

An intermediate layer including at least one of elements constituting a phase change material and silicon is arranged between a recording layer composed of the phase change material and an n+ polysilicon film to reduce contact resistance between the recording layer and the n+ polysilicon film, thereby simplifying the structure of a phase change memory and reducing the cost thereof. If the phase change material contains Ge, Sb, and Te, for example, the intermediate layer includes at least one of Si—Sb, Si—Te, and Si—Ge.