Pectin-Modified Resistant Starch via Enzymatic Cross-Linking

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing starches are either quickly digestible, leading to rapid glucose release, or lack sufficient dietary fiber, making them unsuitable for providing sustained energy and high fiber content needed for health benefits and calorie management.

Innovation Solution

Cross-linking starch with pectin using pectinesterase to create a resistant starch with lower digestibility and higher dietary fiber content, achieved through an enzymatic reaction that modifies the starch's physicochemical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If starch is quickly digestible, then energy release is rapid, but glucose levels spike and calorie management becomes difficult

Engineering Contradiction:
Improvedigestion speedVSAvoidrapid glucose release
Core Design Contradiction:
SpeedVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite material by cross-linking starch with pectin through enzymatic reaction. This composite structure (pectin-modified resistant starch) combines the properties of both starch and pectin, forming a complex matrix that resists enzymatic digestion while maintaining carbohydrate content, thus providing slow glucose release and sustained energy without rapid spikes

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physicochemical parameters of starch by modifying its molecular structure through pectin cross-linking. This structural modification transforms ordinary digestible starch into resistant starch with altered digestibility parameters, enabling slow release of glucose over extended periods while maintaining caloric content

Inventive Principle:
Principle #35Parameter changes

2Reliability

If chemically modified starch is used to create resistant starch, then digestion resistance is achieved, but safety and edibility are compromised

Engineering Contradiction:
Improvedigestion resistanceVSAvoidchemical safety
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces chemical modification methods with enzymatic modification. Instead of using chemical agents to cross-link starch (as in conventional methods), the invention uses pectinesterase enzyme to catalyze the cross-linking reaction between starch and pectin, producing a safe, edible resistant starch that maintains digestion resistance without chemical hazards

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces pectinesterase enzyme as an intermediary catalyst to facilitate the cross-linking reaction between starch and pectin. This enzymatic intermediary enables the formation of resistant starch through a biological process rather than direct chemical reaction, ensuring the product's safety and edibility while achieving the desired digestion resistance

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting resistant starch slows glucose release, providing a low-calorie, high-fiber carbohydrate source suitable for managing glucose levels and enhancing energy sustainability, making it beneficial for health and medical applications.

Implementation Method 1

cross-linking starch with pectin by pectinesterase reaction

Methodology Applied
Scientific EffectEnzymatic reaction: Enzyme

Implementation Method 2

cross-linking starch with pectin by pectinesterase reaction so as to reduce the digestibility of the starch

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Implementation Method 3

resist digestion by α-amylase

Methodology Applied
Scientific EffectEnzymatic hydrolysis resistance: Enzyme

Data Source

PatentEP2057906B1Pectin-modified resistant starch, a composition containing the same and method for preparing resistant starch
Publication Date: 2012.06.27 FOOD IND RES & DEV INST
  • EP2057906B1 patent drawing
  • EP2057906B1 patent drawing
  • EP2057906B1 patent drawing

AI summary

This invention relates to a pectin-modified resistant starch prepared by cross-linking starch with pectin by pectinesterase reaction. Such resistant starch is low amylase digestible and thus is useful in food products, including nutritional supplements, to reduce calorie content and increase fiber content. This invention also relates to a composition containing the resistant starch and a process for the preparation of the same.