Phase Change Material With Insulating Impurities For PRAM

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Solution Overview

Problem

Conventional PRAMs face challenges in increasing integration level due to high reset current requirements and sensitivity to environmental factors, which affect reliability and retention properties.

Innovation Solution

A phase changing material with uniformly distributed insulating impurities, such as SiOx, SiN, or Al2O3, is used in the phase change layer, reducing the amorphorization temperature and increasing the crystallization temperature, thereby lowering the reset current and improving retention characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the size of transistors and storage nodes is reduced to increase integration level, then the integration level increases, but the maximum allowable current of the transistor decreases making it difficult to reduce reset current

Engineering Contradiction:
Improveintegration levelVSAvoidmaximum allowable current
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The invention changes the material composition parameters of the phase change layer by incorporating insulating impurities (such as silicon oxide, silicon nitride, or aluminum oxide) at concentrations of 1-50 atomic percent. This material parameter change modifies the phase transition characteristics, enabling reset current reduction to below 100 µA, which resolves the contradiction between miniaturization and current capability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite phase change material by combining conventional phase change materials (such as Ge-Sb-Te alloys) with insulating impurities. This composite structure allows the material to maintain its phase change functionality while introducing insulating properties that reduce the reset current requirement, thereby enabling higher integration levels without sacrificing current capability.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the crystallization temperature is lowered to facilitate phase change, then the phase change process becomes easier, but the device becomes more sensitive to surrounding environment degrading reliability and retention

Engineering Contradiction:
Improvephase change processVSAvoidretention properties
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention optimizes the crystallization temperature parameter to a specific range (200-400°C) through material composition adjustment. This parameter optimization ensures that the phase change process remains facilitable while the crystallization temperature is high enough to provide thermal stability and resistance to environmental fluctuations, thereby maintaining reliability and retention properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces insulating impurities locally within the phase change layer to create regions with modified thermal and electrical properties. These locally modified regions facilitate phase change at lower temperatures while the overall material maintains high crystallization temperature for stability, resolving the contradiction between ease of operation and reliability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution decreases the reset current and enhances the retention properties of PRAMs, allowing for reduced transistor size and improved integration level without increasing set resistance, while maintaining stable data retention.

Implementation Method 1

a phase change layer where data is stored may change between crystalline and amorphous depending on temperature

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

A phase changing material with uniformly distributed insulating impurities, such as SiOx, SiN, or Al2O3, is used in the phase change layer, reducing the amorphorization temperature and increasing the crystallization temperature

Methodology Applied
Scientific EffectThermal property modification:

Implementation Method 3

a lower electrode contact layer formed on the lower electrode... a material that has a negative Seebeck coefficient with a larger absolute value than TiN or TiAlN

Methodology Applied
Scientific EffectPeltier effect: Peltier Effect

Data Source

PatentUS7956342B2Phase change material for use in a phase change random access memory, the phase change material having uniformly distributed insulating impurities
Publication Date: 2011.06.07 SAMSUNG ELECTRONICS CO LTD
  • US7956342B2 patent drawing
  • US7956342B2 patent drawing
  • US7956342B2 patent drawing

AI summary

Insulating impurities may be uniformly distributed over an entire or partial region of the phase change material. The PRAM may include a phase change layer including the phase change material. The insulating impurity content of the phase change material may be 0.1 to 10% (inclusive) the volume of the phase change material. The insulating impurity content of the phase change material may be adjusted by controlling the power applied to a target including the insulating impurities.