Phase Change Memory Cell High Temperature Data Retention

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Solution Overview

Problem

Phase change memory cells face data loss or degradation at high temperatures due to crystallization and nucleation of the phase change material, which affects data retention.

Innovation Solution

A phase change memory cell using growth-dominated phase change material operated at over-reset conditions, ensuring the active volume remains in an amorphous state without poly-crystalline phases, with insulation and specific electrode materials, and employing higher reset currents to maintain data integrity at temperatures above 150 degrees Celsius.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If material with high crystallization temperature is used, then high temperature operation capability is improved, but crystallization still occurs at elevated temperatures causing data loss

Engineering Contradiction:
Improveoperating temperature rangeVSAvoiddata retention
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the material parameters by using a specific chalcogenide alloy composition (Ge-Sb-Te-In) with controlled stoichiometry ratios. By adjusting the chemical composition parameters, the material achieves a balance between maintaining structural stability at high temperatures and preventing unwanted crystallization, thereby extending the operating temperature range while preserving data retention reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite phase change material system combining multiple elements (Ge, Sb, Te, In) in specific proportions. This composite structure leverages the beneficial properties of each element: Ge provides phase change characteristics, Sb enhances stability, Te enables amorphous structure formation, and In suppresses crystallization. The composite material thus achieves both high-temperature operation capability and data retention

Inventive Principle:
Principle #40Composite materials

2Loss of information

If the phase change material is quenched into amorphous state, then data storage capability is improved, but the surrounding crystalline layer acts as a seed for growth at high temperatures

Engineering Contradiction:
Improvedata storage integrityVSAvoidphase stability
Core Design Contradiction:
Loss of informationVSStability of the object's composition

Solution Approach 1:

The patent extracts or removes the harmful crystalline layer that surrounds the amorphous phase change material. By eliminating this crystalline environment that would otherwise act as a nucleation seed, the patent prevents temperature-induced crystallization while maintaining the data-storing amorphous state, thus preserving both data integrity and phase stability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces an intermediate encapsulation layer between the phase change material and the external environment. This intermediary layer acts as a protective barrier that isolates the amorphous phase from thermal effects and prevents crystallization by blocking the propagation of crystalline structures, thereby maintaining phase stability while preserving data storage capability

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If higher reset currents are applied to maintain amorphous state at high temperatures, then data retention is improved, but energy consumption increases

Engineering Contradiction:
Improvedata retention at high temperatureVSAvoidreset current energy
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the material parameters by using a specific chalcogenide alloy composition (Ge-Sb-Te-In) with controlled stoichiometry ratios. By adjusting the chemical composition parameters, the material achieves a balance between maintaining structural stability at high temperatures and preventing unwanted crystallization, thereby extending the operating temperature range while preserving data retention reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potentially harmful high-temperature environment into a beneficial condition by utilizing the specific thermal and electrical properties of the Ge-Sb-Te-In alloy. The material's unique phase transition characteristics at elevated temperatures are harnessed to enhance data retention, transforming the thermal challenge into a functional advantage that allows reliable operation in high-temperature conditions

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides superior data retention qualities at high temperatures by preventing crystallization and maintaining the amorphous state, thus ensuring reliable data storage.

Implementation Method 1

Phase change material has a variety of applications in microelectronic devices such as optical storage media and solid state phase change memory devices. Phase change random access memory (PRAM) devices, for example, store data using a phase change material, such as, for example, a chalcogenide alloy, that transforms into a crystalline state or an amorphous state during cooling after a heat treatment.

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

A current passed through the phase change material creates ohmic heating and causes the phase change material to melt.

Methodology Applied
Scientific EffectOhmic heating: Joule Heating

Implementation Method 3

Melting and abruptly cooling the phase change material quenches the phase change material into the amorphous state.

Methodology Applied
Scientific EffectQuenching: Cooling

Data Source

PatentUS8233317B2Phase change memory device suitable for high temperature operation
Publication Date: 2012.07.31 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US8233317B2 patent drawing
  • US8233317B2 patent drawing
  • US8233317B2 patent drawing

AI summary

A phase change memory cell that includes a bottom electrode, a top electrode separated from the bottom electrode, and growth-dominated phase change material deposited between the bottom electrode and the top electrode and contacting the bottom electrode and the top electrode and surrounded by insulation material at sidewalls thereof. The phase change memory cell in a reset state only includes an amorphous phase of the growth-dominated phase change material within an active volume of the phase change memory cell.