Lattice-Matched Photocathode Epitaxy for Extended IR Detection

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Solution Overview

Problem

Current night vision systems using Gen III photocathodes with ternary materials on binary substrates suffer from lattice mismatches, leading to reduced imaging performance and limited wavelength sensitivity, making them unsuitable for applications requiring sensitivity up to 1550 nm, such as high-power laser guidance and rangefinders.

Innovation Solution

The development of a photocathode epitaxial structure with a binary compound substrate and an active device absorber layer made of quaternary or greater compound semiconductor materials, which are lattice-matched to minimize strain and extend wavelength sensitivity, using materials like InGaAsNSb or InGaAsP to achieve a lower bandgap and increased sensitivity up to 1550 nm.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If ternary materials (e.g., InGaAs) are formed on binary substrates (e.g., GaAs) to extend wavelength sensitivity, then wavelength sensitivity is improved, but lattice mismatches cause strain that reduces imaging performance

Engineering Contradiction:
Improvewavelength sensitivityVSAvoidimaging performance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent uses quaternary compound semiconductor materials (e.g., InGaAsP, InGaAsN) as composite materials that combine the benefits of extended wavelength sensitivity with lattice matching capability. These composite materials allow simultaneous achievement of both improved wavelength sensitivity and reduced strain compared to simple ternary materials on binary substrates.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameters by transitioning from ternary to quaternary compounds, adjusting the stoichiometric ratios and elemental composition to achieve both extended wavelength response and lattice matching with the substrate, thereby resolving the contradiction between sensitivity extension and performance maintenance.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If photocathodes are designed for extended wavelength sensitivity up to 1550 nm, then sensitivity for laser detection is improved, but current technology reduces overall sensitivity across the usable spectrum

Engineering Contradiction:
Improvewavelength sensitivity rangeVSAvoidoverall sensitivity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent optimizes the bandgap energy parameter and material composition of the quaternary semiconductor to achieve a balance that maintains high quantum efficiency across the entire usable spectrum while extending sensitivity to 1550 nm, preventing the trade-off that plagues current technology.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The use of quaternary compound semiconductors provides a composite material solution that simultaneously achieves extended long-wavelength sensitivity and maintains high overall quantum efficiency across the spectrum, avoiding the sensitivity losses associated with current ternary material approaches.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution reduces strain and enhances wavelength sensitivity, improving Quantum Efficiency (QE) and reducing Equivalent Background Illumination (EBI), allowing for broader spectral sensitivity and improved performance in night vision systems for applications like laser guidance and celestial observation.

Implementation Method 1

an active device absorber layer forming a portion of a p-type device photocathode formed on the binary compound substrate material. The active device absorber layer comprising at least a quaternary or greater compound semiconductor material structure configured to be adequately (i.e., remains unrelaxed) lattice matched with the substrate material

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentEP4376044A1Design of lattice matched photocathodes for extended wavelengths
Publication Date: 2024.05.29 L3HARRIS TECH INC
  • EP4376044A1 patent drawingFigure 1
  • EP4376044A1 patent drawingFigure 2
  • EP4376044A1 patent drawingFigure 3~4

AI summary

A photocathode epitaxial structure. The photocathode epitaxial structure includes a binary compound substrate material. The photocathode epitaxial structure further includes an active device absorber layer forming a portion of a p-type device photocathode formed on the binary compound substrate material. The active device absorber layer comprising at least a quaternary or greater material structure configured to be lattice matched with the substrate material to reduce strain to allow charge carriers to go further in the active device absorber layer implemented in the photocathode of a nightvision system.