Photosensitive Polymeric Microparticles Self-Assembly

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Solution Overview

Problem

Current products incorporating core/shell microparticles with photosensitive properties lack control over the properties of the photosensitive materials, limiting their performance and applications.

Innovation Solution

An aqueous composition comprising a photosensitive material and a polymerizable component with hydrophilic and hydrophobic monomers, which self-assemble to form crosslinked photosensitive polymeric microparticles, allowing for controlled properties and enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If core/shell microparticles with photosensitive properties are used, then photosensitive functionality is achieved, but control over the properties of the photosensitive materials is limited

Engineering Contradiction:
Improvecontrol over photosensitive material propertiesVSAvoidmicroparticle structure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by creating distinct hydrophilic and hydrophobic domains within the microparticle structure. The hydrophilic monomers form water-soluble regions while hydrophobic monomers form separate regions, allowing the photosensitive material to be selectively positioned and controlled within specific domains of the microparticle, thereby achieving property control without excessive complexity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining hydrophilic monomers, hydrophobic monomers, and photosensitive materials into a single microparticle system. This composite approach allows different functional components to work together, providing both the structural integrity needed and the controlled photosensitive properties through the synergistic interaction of the composite components

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If hydrophilic and hydrophobic monomers are combined to form microparticles, then controlled properties are achieved, but manufacturing process complexity increases

Engineering Contradiction:
Improvemicroparticle property controlVSAvoidmanufacturing process simplicity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-selecting and combining specific hydrophilic and hydrophobic monomers with defined properties before the microparticle formation process. This preliminary characterization and selection of monomer components allows for predictable self-assembly behavior and controlled microparticle properties, reducing the need for complex real-time manufacturing adjustments

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes self-service through the self-assembly mechanism where hydrophilic and hydrophobic monomers automatically organize into microparticles with controlled structures based on their inherent amphiphilic properties. This self-organizing behavior eliminates the need for complex external control mechanisms during manufacturing, achieving precision without proportional increases in process complexity

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables controlled properties of photosensitive materials, improving their performance and versatility in applications such as optical elements and display devices.

Implementation Method 1

at least one polymerizable component comprising at least one substantially hydrophilic monomer and at least one substantially hydrophobic monomer, the hydrophilic monomer and the hydrophobic monomer being adapted to combine and at least partially form microparticles

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

This response can be a type of luminescence in which visible radiation is emitted by a photosensitive material after exposure, e.g., fluorescent and phosphorescent materials

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 3

This response can be a type of luminescence in which visible radiation is emitted by a photosensitive material after exposure, e.g., fluorescent and phosphorescent materials

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 4

in which there is a reversible change in color, e.g., photochromic materials

Methodology Applied
Scientific EffectPhotochromism: Photochromism

Implementation Method 5

at least one polymerizable component comprising at least one substantially hydrophilic monomer and at least one substantially hydrophobic monomer, the hydrophilic monomer and the hydrophobic monomer being adapted to combine and at least partially form microparticles

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS8153344B2Methods for producing photosensitive microparticles, aqueous compositions thereof and articles prepared therewith
Publication Date: 2012.04.10 TRANSITIONS OPTICAL INC

AI summary

Described are aqueous compositions of an effective amount of at least one photosensitive material and at least one polymerizable component that are adapted to at least partially form photosensitive microparticles or at least partially crosslinked photosensitive polymeric microparticles. The photosensitive polymeric microparticles are made of integral surface and interior domains wherein at least one of the surface and/or interior domains is photosensitive. Also described are aqueous dispersions of such microparticles, ways of producing such microparticles and photosensitive articles such as optical elements that incorporate the photosensitive polymeric microparticles.