Low-Temperature Photosensitive Resin for OLED Anti-Reflection

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Solution Overview

Problem

OLED devices face challenges with reflection reduction using polarized films, which degrade emission efficiency and increase manufacturing costs, and existing anti-reflective solutions for OLEDs require high-temperature processes, limiting effective low-temperature curing options.

Innovation Solution

A photosensitive resin composition capable of low-temperature curing, comprising a first binder resin with an unsaturated ethylene-based group and a second binder resin, along with a photo cross-linking agent, thermal curing agent, and photoinitiator, to form a film with excellent anti-reflection properties suitable for OLED devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a polarized film is used to prevent or reduce reflection of external light, then the reflection is reduced, but the emission efficiency of the OLED device deteriorates and the manufacturing cost increases

Engineering Contradiction:
Improvereflection of external lightVSAvoidemission efficiency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the optical parameters of the color filter by introducing a specific refractive index range (1.3 to 1.8) and controlling film thickness (50-200 nm) to achieve anti-reflection functionality. This transforms the color filter from a simple color selection component to an active anti-reflection element, reducing external light reflection while maintaining OLED emission efficiency without requiring additional polarized films

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent makes the color filter perform multiple functions: it maintains its original color selection function while simultaneously providing anti-reflection functionality through the integrated low-refractive-index layer. This multi-functional design eliminates the need for separate polarized films, reducing manufacturing cost and improving emission efficiency

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of manufacture

If an anti-reflective color filter is used instead of a polarized film, then the manufacturing cost is reduced and emission efficiency is improved, but the curing process requires high temperature (200°C or higher)

Engineering Contradiction:
Improvemanufacturing costVSAvoidcuring temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the resin material to achieve low-temperature curing. By selecting specific resins with appropriate glass transition temperatures and curing characteristics, the formulation enables complete curing at temperatures below 100°C, making the process compatible with OLED manufacturing constraints

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining a low-refractive-index layer with specific resin components (acrylic resins, vinyl resins, or epoxy resins) and crosslinking agents. This composite formulation achieves both the optical properties needed for anti-reflection and the chemical properties needed for low-temperature curing

Inventive Principle:
Principle #40Composite materials

3Temperature

If a low-temperature curing process is used, then the manufacturing process becomes compatible with OLED devices, but the curing completeness and film quality may be compromised

Engineering Contradiction:
Improvecuring temperatureVSAvoidcuring completeness
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent introduces crosslinking agents as intermediaries that facilitate complete curing at low temperatures. These crosslinking agents (such as glycidyl methacrylate, pentaerythritol tetraacrylate, or diamine compounds) mediate the curing reaction, enabling the resin to achieve complete crosslinking and film formation at temperatures below 100°C without compromising curing completeness

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the molecular weight and functional group content of the resin components to enable low-temperature curing. By controlling parameters such as the weight average molecular weight (10,000-100,000) and the content of reactive functional groups, the formulation achieves complete curing at low temperatures while maintaining film quality and curing completeness

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The low-temperature-cured film achieves high transmittance, improved chemical resistance, and excellent pattern straightness, enhancing OLED efficiency and reducing manufacturing costs by eliminating the need for high-temperature processes.

Implementation Method 1

a photosensitive resin composition capable of being cured at a low temperature... comprising a first binder resin with an unsaturated ethylene-based group... and a photoinitiator

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS10042253B2Photosensitive resin composition, film prepared by using the photosensitive resin composition, and organic light-emitting display device including the film
Publication Date: 2018.08.07 SAMSUNG DISPLAY CO LTD
  • US10042253B2 patent drawing
  • US10042253B2 patent drawing
  • US10042253B2 patent drawing

AI summary

A photosensitive resin composition includes a first binder resin represented by Formula 1. The photosensitive resin composition may be cured at a low temperature (e.g., about 0° C. to about 100° C., about 40° C. to about 100° C., or about 70° C. to about 100° C.). A film may be formed from the photosensitive resin composition. An organic light-emitting display (OLED) device may include the film prepared from the photosensitive resin composition.