Photosensitive Resin Remover Composition for Semiconductor Fabrication

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Solution Overview

Problem

The existing methods for removing photosensitive resin patterns in semiconductor device fabrication face challenges such as corrosion of metal patterns and incomplete removal of byproducts, which affect the precision and efficiency of the etching and plating processes.

Innovation Solution

A photosensitive-resin remover composition comprising an amine compound, de-ionized water, a removing accelerator, and a corrosion inhibitor, with specific formulations and ratios, is used to effectively remove photosensitive resin patterns and byproducts without corroding metal patterns, enhancing the removal process's efficiency and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional photosensitive-resin remover is used, then photosensitive resin can be removed, but metal patterns are corroded

Engineering Contradiction:
Improvemetal pattern integrityVSAvoidmetal corrosion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the remover composition by specifying precise ratios of amine compound (0.1-10 wt%), organic solvent (85-99.9 wt%), and corrosion inhibitor (0.1-5 wt%). This optimized composition achieves effective photosensitive resin removal while minimizing metal pattern corrosion through controlled chemical reactivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The corrosion inhibitor acts as an intermediary substance that protects metal patterns from the harmful effects of the remover composition. It mediates between the aggressive remover chemicals and the metal patterns, preventing direct corrosive interaction while allowing photosensitive resin removal.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If strong remover composition is used to remove hardened photosensitive resin, then removal efficiency increases, but metal corrosion increases

Engineering Contradiction:
Improveremoval efficiencyVSAvoidmetal corrosion
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite remover composition combining multiple functional components: amine compound for primary removal action, organic solvent for dissolution and penetration, and corrosion inhibitor for metal protection. This composite formulation achieves high removal efficiency on hardened photosensitive resin while the corrosion inhibitor component simultaneously protects metal patterns from damage.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If conventional remover composition is used, then photosensitive resin removal is achieved, but byproducts remain on metal patterns

Engineering Contradiction:
Improvepattern cleanlinessVSAvoidbyproduct residue
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the composition parameters including amine compound concentration (0.1-10 wt%), organic solvent type and amount (85-99.9 wt%), and corrosion inhibitor content (0.1-5 wt%). This precise parameter control ensures complete removal of photosensitive resin and its byproducts from metal patterns, achieving clean surfaces without residue.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition allows for clean removal of hardened or degenerated photosensitive resin and byproducts, reducing reaction time and minimizing metal corrosion, thereby improving the productivity and reliability of semiconductor device fabrication.

Implementation Method 1

a photosensitive-resin remover composition, including an amine compound and de-ionized water

Methodology Applied
Scientific EffectChemical dissolution: Solvation

Implementation Method 2

photosensitive resin byproducts degenerated in the etching process may be cleanly removed

Methodology Applied
Scientific EffectChemical degradation: Decomposition (biological)

Implementation Method 3

The photosensitive-resin remover composition may further include a corrosion inhibitor, the corrosion inhibitor being at least one of an aromatic mercapto compound, an organic compound, and an anhydride including a carboxylic group

Methodology Applied
Scientific EffectCorrosion inhibition:

Data Source

PatentUS8129322B2Photosensitive-resin remover composition and method of fabricating semiconductor device using the same
Publication Date: 2012.03.06 SAMSUNG ELECTRONICS CO LTD
  • US8129322B2 patent drawing
  • US8129322B2 patent drawing
  • US8129322B2 patent drawing

AI summary

A photosensitive-resin remover composition includes an amine compound and de-ionized water, an amount of the de-ionized water being about 45% to about 99% by weight based on a total weight of the composition.