Photosensitive Surface Treatment for Resist-Free Fine Metal Patterning

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Solution Overview

Problem

Existing pattern formation methods for microdevices require complex processes involving photoresists, developing, and etching, which are time-consuming and costly.

Innovation Solution

A photosensitive surface treating agent containing a compound represented by Formula (M1) is used, which generates amines on the substrate surface upon light exposure, allowing for the direct adherence of metal, organic, or inorganic materials without the need for photoresists or etching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional pattern formation methods using photoresists and etching are employed, then metal patterns can be formed on the substrate, but the process becomes complex and time-consuming

Engineering Contradiction:
Improvepattern formation precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the photoresist and etching steps from the conventional pattern formation process. By using a photosensitive surface treating agent that directly generates chemically active substituents upon light exposure, the complex multi-step process (photoresist coating, exposure, development, etching) is reduced to a simpler process (applying surface treating agent, exposure, metal deposition), thereby reducing device complexity while maintaining pattern formation precision

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The photosensitive surface treating agent performs multiple functions: it acts as both the surface treatment layer and the pattern definition layer. Upon light exposure, it simultaneously creates the chemical gradient needed for metal adhesion and defines the pattern geometry, eliminating the need for separate photoresist and etching processes

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Manufacturing precision

If conventional pattern formation methods with multiple steps are used, then metal patterns can be formed, but production time increases

Engineering Contradiction:
Improvepattern formation precisionVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The invention merges the surface treatment function and pattern definition function into a single photosensitive surface treating agent layer. This consolidation reduces the number of sequential steps from multiple (surface treatment, photoresist coating, exposure, development, etching) to fewer (applying surface treating agent, exposure, metal deposition), thereby improving productivity while maintaining manufacturing precision

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The photosensitive surface treating agent is applied in advance to the substrate before metal deposition. This preliminary action creates a surface that will selectively adhere metal only in exposed regions, eliminating the need for subsequent etching or photoresist removal steps, thus accelerating production

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If conventional photoresist and etching processes are employed, then metal patterns can be formed, but production costs increase

Engineering Contradiction:
Improvepattern formation precisionVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The photosensitive surface treating agent functions as a disposable layer that is applied, exposed, and then effectively discarded or integrated into the final structure. This eliminates the need for expensive photoresist materials, development chemicals, and etching equipment, reducing manufacturing costs while maintaining pattern formation precision through the chemical gradient mechanism

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of fine metal patterns with line widths of 3 μm or less on the substrate surface without the need for photoresists or etching, simplifying the process and reducing costs.

Implementation Method 1

a photosensitive surface treating agent containing a compound represented by Formula (M1)... generates amines on the substrate surface upon light exposure

Methodology Applied
Scientific EffectPhotochemical reaction: Photopolymerisation

Data Source

PatentUS20250180990A1Photosensitive surface treating agent, laminate, pattern formation substrate, transistor, pattern forming method and method of producing transistor
Publication Date: 2025.06.05 NIKON CORP
  • US20250180990A1 patent drawing
  • US20250180990A1 patent drawing
  • US20250180990A1 patent drawing

AI summary

A photosensitive surface treating agent containing a compound represented by the following Formula (M1). In Formula (M1), R1 is a linear, branched or cyclic alkyl group having 1 to 6 carbon atoms, Y1 is a linear or branched alkylene group having 1 to 4 carbon atoms or a single bond, and the terminal carbon atom of the alkyl group for R1 may be bonded to a carbon atom constituting the alkylene group for Y1, and R1 and Y1 may form a ring. R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R3 and R4 are each independently an alkyl group having 1 to 3 carbon atoms, n0 is an integer of 0 or more, and X is a halogen atom or an alkoxy group.