Pigment Paste Viscosity Control via Wetting Agents

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Solution Overview

Problem

Pigment pastes with high solids content often have excessively high viscosity, making them difficult to process with conventional automatic mixing machines, leading to inconsistent color and potential contamination issues.

Innovation Solution

Incorporating a wetting agent, such as alkylphenol polyoxyethylene condensates or fatty alcohol ethoxylates, to reduce the viscosity of pigment pastes containing alkyd resin, allowing for a solids content of over 60% while maintaining a suitable viscosity for processing, typically between 0.1 to 8 Pas, and reducing the organic solvent content to less than 300 g/l.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the solids content of pigment paste is increased to reduce VOC content and improve logistics efficiency, then the viscosity of the paste increases excessively, making it difficult to process with conventional automatic mixing machines

Engineering Contradiction:
Improvesolids contentVSAvoidviscosity
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

A wetting agent is introduced as an intermediary substance to modify the interaction between pigment particles and the continuous phase. The wetting agent adsorbs at the pigment surface, reducing interfacial tension and preventing agglomeration, thereby maintaining low viscosity even at high solids content (up to 80% by weight).

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the paste by incorporating specific wetting agents (such as alkylphenol polyoxyethylene condensates or fatty alcohol ethoxylates) in optimized concentrations. This parameter modification allows the system to achieve both high solids content and processable viscosity simultaneously.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional automatic mixing machines are used to process high viscosity pigment pastes, then insufficient drop shape is obtained, leading to color inconsistency and contamination

Engineering Contradiction:
Improvemixing consistencyVSAvoidflowability
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The wetting agent serves as a mediator that improves the flow characteristics of the pigment paste, enabling it to form proper drops during automated dispensing. This ensures consistent dosing and prevents contamination strings from forming during the mixing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If alkyd resins with low viscosity are used to maintain processability, then the resin is difficult to synthesize and becomes cost-intensive

Engineering Contradiction:
ImproveviscosityVSAvoidsynthesis complexity
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

Instead of modifying the alkyd resin itself (which would increase manufacturing complexity), a wetting agent is added as an external intermediary to achieve the desired viscosity reduction. This approach maintains the simplicity of alkyd resin synthesis while still achieving processable paste viscosity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent uses commercially available wetting agents as inexpensive additives to achieve viscosity control, rather than investing in complex custom resin synthesis. The wetting agent provides a cost-effective solution to the viscosity problem.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of wetting agents in pigment pastes with alkyd resin enables them to be flowable and pumpable, facilitating precise dosing and mixing, while maintaining a low VOC content and preventing settling, thus ensuring consistent color and compliance with environmental regulations.

Implementation Method 1

the selection of resin is an essential aspect for the practical applicability of pigment pastes... the function of which is to wet the pigments

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP2243808B1Pigment paste
Publication Date: 2016.12.21 BRILLUX GMBH & CO KG

AI summary

Pigment paste comprises at least an organic solvent, at least a pigment, at least an alkyd resin with a viscosity of at least 5 Pas measured at -23[deg] C and shear rate of 100 per second, and at least a crosslinking agent, where the pigment paste: exhibits a viscosity of 0.1-8, preferably 0.3-1 Pas measured at 23[deg] C and a shear rate of 100 per second, and contains at least 60 wt.% of solid material. An independent claim is included for an antisettling agent comprising the pigment paste and at least a primary color.