Plasma-Coated Boron Nitride Powder for Wash-Resistant Hydrophobicity

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Solution Overview

Problem

Existing methods for forming hydrophobic or water-repellent layers on boron nitride powders are inefficient in ensuring durability and stability, particularly in maintaining water-repellency after ultrasonic washing.

Innovation Solution

A plasma treatment method using a silicon-containing organic compound, such as hexamethyldisiloxane, is applied to form a water-repellent coating layer on boron nitride powders, which chemically bonds to the surface and remains intact after washing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a water-repellent coating layer is formed on boron nitride powders using conventional methods, then water-repellency is achieved, but the coating layer is removed during ultrasonic washing, losing water-repellency

Engineering Contradiction:
Improvewater-repellency durabilityVSAvoidcoating layer stability after washing
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention changes the chemical composition parameters of the coating layer by using silicon-containing organic compounds with specific molecular structures (such as hexamethyldisiloxane, tetraethoxysilane, or trimethylchlorosilane) as precursors. This chemical parameter change enables the coating layer to achieve both water-repellency and resistance to ultrasonic washing, resolving the contradiction between water-repellency durability and coating stability after washing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating layer by incorporating silicon-containing organic compounds that form a hybrid structure on the boron nitride surface. This composite material approach allows the coating to simultaneously exhibit hydrophobic properties and mechanical stability during ultrasonic washing, addressing the contradiction between water-repellency and washing durability

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If plasma treatment is used to form a hydrophobic layer on particles, then hydrophobicity and coating thickness can be controlled, but the coating may not withstand ultrasonic washing

Engineering Contradiction:
Improvecoating thickness controlVSAvoidcoating durability after washing
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention optimizes plasma treatment parameters including precursor material selection (silicon-containing organic compounds), plasma power, treatment time, and atmospheric conditions. By precisely controlling these parameters, the coating achieves optimal thickness and chemical composition that provides both hydrophobicity and ultrasonic washing resistance, resolving the contradiction between manufacturing precision and coating durability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves continuous water-repellency and hydrophobicity on boron nitride powders, preventing agglomeration and enabling stable dispersion in non-polar solvents.

Implementation Method 1

performing plasma treatment on the boron nitride powders

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

an organic compound containing silicon as a precursor is vaporized to produce an atmosphere

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 3

the water-repellent coating layer chemically bonds to the boron nitride

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS12410055B2Method for water-repellent treatment of boron nitride powder and water-repellent-treated boron nitride
Publication Date: 2025.09.09 KOREA INST OF FUSION ENERGY
  • US12410055B2 patent drawing
  • US12410055B2 patent drawing
  • US12410055B2 patent drawing

AI summary

A method for water-repellent coating treatment of a boron nitride powders and water-repellent treated boron nitride are disclosed. The method includes producing a water-repellent coating layer on the surface of the boron nitride powders by plasma treatment using a silicon-containing organic compound containing silicone, wherein the water-repellent coating layer remains on the boron nitride through chemical binding with the boron nitride even after ultrasonic water washing.