Plasma Doping Fin-FETs with Oxygen for Low Resistance

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Solution Overview

Problem

Existing plasma doping techniques struggle to form low-resistance impurity regions on the side surfaces of fin-semiconductor regions in fin-FETs due to insufficient impurity adsorption and activation, leading to difficulties in achieving desired transistor properties.

Innovation Solution

Incorporating a slight amount of oxygen into the plasma doping process using impurity-containing gases like AsH3, which forms a thin oxide layer to reduce impurity diffusion and enhance activation through oxidation-enhanced diffusion, thereby reducing the resistance in the impurity regions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If plasma doping is performed without oxygen-containing gas, then impurity adsorption is enhanced, but resistance in the impurity region cannot be sufficiently reduced

Engineering Contradiction:
Improveimpurity adsorptionVSAvoidresistance control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameter of the plasma environment by introducing oxygen-containing gas (O2, H2O, N2O, or CO2) at controlled concentrations (0.01-5% by mass) to modify the doping mechanism and achieve lower resistance through oxidation-enhanced diffusion

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces oxygen as an intermediary substance that facilitates impurity activation and reduces resistance through oxidation-enhanced diffusion, acting as a mediator between the impurity atoms and the semiconductor lattice

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If oxygen-containing gas is added to plasma doping, then resistance in impurity region is reduced, but oxidation of fin-semiconductor region may occur

Engineering Contradiction:
Improveresistance controlVSAvoidoxidation damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent precisely controls the oxygen concentration parameter (0.01-5% by mass) and process conditions to enable oxidation-enhanced diffusion while suppressing harmful oxidation of the fin-semiconductor region, transforming oxidation from a harmful effect to a useful mechanism

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates different local conditions: oxidation-enhanced diffusion occurs locally at the impurity doping sites to reduce resistance, while the overall fin-semiconductor region is protected from harmful oxidation through controlled plasma parameters and timing

Inventive Principle:
Principle #3Local quality

3Ease of operation

If ion implantation is performed in oblique direction, then side portions of fin-type silicon region are doped, but doping uniformity is poor and resistance is high

Engineering Contradiction:
Improveside surface doping capabilityVSAvoiddoping uniformity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent replaces the mechanical ion implantation process with a plasma-based chemical doping process, where impurity atoms are transported and incorporated through plasma chemistry and diffusion mechanisms rather than mechanical ion bombardment, achieving uniform doping without oblique angle requirements

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces the resistance in the impurity regions of fin-semiconductor devices, enabling the formation of fin-type semiconductor devices with desired properties by improving impurity activation and minimizing issues like amorphization and corner chipping.

Implementation Method 1

Incorporating a slight amount of oxygen into the plasma doping process using impurity-containing gases like AsH3, which forms a thin oxide layer to reduce impurity diffusion and enhance activation through oxidation-enhanced diffusion

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

plasma doping process using impurity-containing gases like AsH3

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

enhance activation through oxidation-enhanced diffusion

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS8574972B2Method for fabricating semiconductor device and plasma doping apparatus
Publication Date: 2013.11.05 SAMSUNG ELECTRONICS CO LTD
  • US8574972B2 patent drawing
  • US8574972B2 patent drawing
  • US8574972B2 patent drawing

AI summary

After a fin-semiconductor region (13) is formed on a substrate (11), impurity-containing gas and oxygen-containing gas are used to perform plasma doping on the fin-semiconductor region (13). This forms impurity-doped region (17) in at least side portions of the fin-semiconductor region (13).