Plasma Nitride SOI Structure for Uniform, Impurity-Resistant Bonding

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Solution Overview

Problem

Current methods for preparing semiconductor-on-insulator (SOI) structures are inefficient due to high costs, material wastage, and lack of thickness uniformity, especially for layers thinner than a few microns, and are sensitive to impurities and defects at the bond interface.

Innovation Solution

A method involving the deposition of a handle semiconductor nitride layer on a handle dielectric layer and bonding a donor dielectric layer to form a multilayer structure with insulating layers such as oxide-nitride-oxide (ONO) to resist impurities and improve layer transfer, using techniques like plasma deposition and annealing to enhance bond strength and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional wafer bonding methods are used to prepare SOI structures, then bonding can be achieved, but the process is sensitive to impurities and defects at the bond interface, resulting in poor reliability

Engineering Contradiction:
Improvebond interface qualityVSAvoidimpurities and defects at bond interface
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A plasma nitride layer is deposited as an intermediary barrier between the handle substrate and the device layer. This nitride layer prevents impurities and defects from the handle substrate from affecting the device layer, while still allowing for successful wafer bonding through plasma activation of the bonding surfaces.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The bonding interface is segmented into multiple functional layers: the handle substrate, the plasma nitride barrier layer, and the device layer. This segmentation isolates the device layer from impurities in the handle substrate while maintaining the structural integrity of the bonded interface.

Inventive Principle:
Principle #1Segmentation

2Productivity

If conventional layer transfer methods are used, then layer transfer can be achieved, but the process is time-consuming and costly with material wastage

Engineering Contradiction:
Improvelayer transfer efficiencyVSAvoidprocessing time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

Plasma nitride deposition and plasma activation are performed as preliminary actions before bonding. These preliminary treatments prepare the surfaces for efficient bonding and layer transfer, eliminating the need for time-consuming post-bonding processing steps and reducing overall manufacturing time.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The process utilizes plasma parameters (power, pressure, gas composition) to control the deposition and activation processes, enabling precise control over layer properties and bonding quality, which improves efficiency and reduces rework.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If thick film device layers are used, then the device layer can be sufficiently thick for certain applications, but thickness uniformity is difficult to achieve for layers thinner than a few microns

Engineering Contradiction:
Improvethickness uniformityVSAvoiddevice layer thickness
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The mechanical grinding process is replaced with plasma-based deposition and activation processes. Plasma deposition provides atomic-layer precision and excellent thickness uniformity, while plasma activation enables clean separation without mechanical contact, achieving uniform thickness even for sub-micron layers.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces costs, improves thickness uniformity, and enhances the resistance of the SOI structure to impurities, resulting in a more efficient and reliable semiconductor-on-insulator layer transfer process.

Implementation Method 1

a plasma nitride layer and method of manufacture thereof

Methodology Applied
Scientific EffectPlasma deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 2

followed by a thermal treatment to strengthen the bond. The anneal may convert the terminal silanol groups to siloxane bonds between the two interfaces, thereby strengthening the bond.

Methodology Applied
Scientific EffectThermal annealing: Annealing

Implementation Method 3

Particles (atoms or ionized atoms, e.g., hydrogen atoms or a combination of hydrogen and helium atoms) are implanted at a specified depth beneath the front surface of the donor wafer. The implanted particles form a cleave plane in the donor wafer at the specified depth at which they were implanted.

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 4

The surfaces of the wafers can be additionally chemically activated by a wet treatment, such as an SC1 clean or hydrofluoric acid. The wet treatment and the plasma activation may occur in either order, or the wafers may be subjected to only one treatment.

Methodology Applied
Scientific EffectPlasma activation: Plasma

Data Source

PatentUS11984348B2Semiconductor on insulator structure comprising a plasma nitride layer and method of manufacture thereof
Publication Date: 2024.05.14 GLOBALWAFERS CO LTD
  • US11984348B2 patent drawing
  • US11984348B2 patent drawing
  • US11984348B2 patent drawing

AI summary

A method is provided for preparing a semiconductor-on-insulator structure comprising a silicon nitride layer deposited by plasma deposition.