3D-Printed Polar Plates with Sintered Conductive Flow Structures

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Solution Overview

Problem

Existing methods for producing polar plates for fuel cells and redox flow batteries face challenges such as mechanical and thermal stresses, burrs, and low electrical and thermal conductance, particularly with traditional machining and 3D printing processes like FFF and FGF, which limit their efficiency and effectiveness.

Innovation Solution

A 3D printing process using a digital model to layer-by-layer apply a composite material, which includes metallic constituents and a binder, followed by debinding and sintering in a hydrogen or argon atmosphere, allowing for the creation of polar plates with optimized conductance and complex internal structures, enabling efficient energy conversion and fluid management.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional machining processes are used to produce polar plates, then manufacturing precision can be achieved, but mechanical stresses and burrs are generated that adversely affect stack connection

Engineering Contradiction:
Improvedimensional accuracyVSAvoidmechanical stresses and burrs
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces traditional mechanical machining processes with electrochemical etching. This substitution eliminates mechanical contact between cutting tools and the polar plate material, thereby preventing the generation of mechanical stresses and burrs while maintaining high dimensional accuracy through controlled electrochemical removal of material.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental parameter of the manufacturing process from mechanical force-based removal to electrochemical reaction-based removal. By controlling electrical parameters (current density, voltage, electrolyte composition) instead of mechanical parameters (cutting force, tool geometry), the process achieves precision without mechanical damage.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If photochemical etching is used to produce polar plates, then mechanical stresses are avoided, but the process is limited to specific metal materials

Engineering Contradiction:
Improvemechanical stressesVSAvoidmaterial selection range
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent extends the material applicability by changing the fundamental mechanism from photochemical etching (which relies on light-sensitive coatings and specific metal reactivity) to electrochemical etching. This allows the process to work with diverse materials including stainless steels, titanium, and other metals that can serve as anodes in electrochemical reactions, significantly broadening material selection flexibility.

Inventive Principle:
Principle #35Parameter changes

3Shape

If CNC machining is used to produce polar plates, then complex shapes can be achieved, but flatness is impaired and stresses are caused

Engineering Contradiction:
Improvecomplex geometryVSAvoidflatness
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent replaces mechanical CNC machining with electrochemical etching. The electrochemical process removes material uniformly through controlled anodic dissolution, maintaining the inherent flatness of the substrate while being capable of creating complex three-dimensional flow channel geometries through mask patterning and controlled etching rates.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process produces polar plates with high specific conductance and design flexibility, reducing material costs and mechanical stresses, enabling efficient energy conversion and fluid management, and allowing for complex internal structures that enhance the performance of fuel cells and redox flow batteries.

Implementation Method 1

The material used for printing is heated by the extruder until it liquefies or melts

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

In debindering, a large part of the binder in the first stage is removed by catalytic decomposition, by thermal vaporization, decomposition or by solvent extraction

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

sintering in a hydrogen or argon atmosphere

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS20240379972A1Improved process for producing a polar plate
Publication Date: 2024.11.14 HOCHSCHULE RHEINMAIN UNIV OF APPLIED SCI WIESBADEN RUSSELSHEIM
  • US20240379972A1 patent drawing
  • US20240379972A1 patent drawing
  • US20240379972A1 patent drawing

AI summary

A process for producing a polar plate for fuel cells and/or redox flow batteries, comprising applying layers to produce a blank, wherein a composite formed of print material is printed layer-by-layer through a nozzle (extruder) using a fused filament fabrication (FFF) process or a fused granular fabrication (FGF) process and applied to a work plane to produce the blank of the polar, and sintering, wherein the blank of the polar plate is heated, with the temperatures during sintering remain below the melting temperature of the print material, so that the form (shape) of the workpiece is retained and to produce a finished polar plate.