Immobilized Cationic Polyelectrolyte Textiles for Chromate Adsorption

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Solution Overview

Problem

Current textile materials are inadequate for effectively adsorbing toxic anionic metal ions like chromates from aqueous solutions due to limited surface functionality, leading to environmental contamination in industrial settings.

Innovation Solution

Immobilization of cationic polyelectrolytes, such as chitosan and polyvinylamine, on textile materials creates a surface capable of binding anionic metal ions through ionic interactions, enhancing adsorption efficiency across various pH ranges.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If textile materials are used as polymeric carrier materials, then accessibility and permeability are improved, but adsorption capacity for anionic metal ions is insufficient

Engineering Contradiction:
Improveaccessibility and permeabilityVSAvoidadsorption capacity for anionic metal ions
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent combines textile materials with cationic polyelectrolytes to create a composite material that integrates the mechanical advantages of textiles (accessibility and permeability) with the high adsorption capacity of polyelectrolytes for anionic metal ions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the surface properties of textile materials by immobilizing cationic polyelectrolytes specifically on the textile surface, creating local regions with high positive charge density that selectively adsorb anionic metal ions while maintaining the bulk textile structure

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The immobilized cationic polyelectrolytes significantly increase the adsorption capacity of textile materials for anionic metal ions like chromates, particularly in acidic to neutral pH conditions, effectively reducing contamination in wastewater.

Implementation Method 1

bind negatively charged ions via ionic interactions

Methodology Applied
Scientific EffectIonic interactions: Ion Repulsion/Attraction

Implementation Method 2

adsorbing the oxometal anions

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2766520B1Materials containing immobilised polyelectrolytes
Publication Date: 2018.03.28 DEUT TEXTILFORSCHUNGSZENTRUM NORD WEST GGMBH
  • EP2766520B1 patent drawingFigure 1~3
  • EP2766520B1 patent drawing
  • EP2766520B1 patent drawing

AI summary

The invention relates to a polymer support material containing immobilized cationic polyelectrolytes which can absorb anionic metal ions from aqueous solutions.