Polymer Foam with Microballoons for Bond Strength

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Solution Overview

Problem

Existing polymer foams produced with hollow microspheres face challenges such as reduced bond strength, mechanical vulnerability, and limited adaptability to surface conditions due to the reduction in foamed structure, leading to inconsistent thickness and mechanical weaknesses under load.

Innovation Solution

A polymer foam with a specific proportion of cavities enclosed by the foam matrix, comprising 6 to 16% volume of microballoons filled with low-boiling liquids or liquefied gas, which expands to form a stable, closed-cell structure with enhanced bonding strength and resilience.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymer foams are produced using hollow microspheres to achieve uniform cell structure and closed-cell configuration, then sealing effect against dust and liquid media is improved, but mechanical vulnerability and reduced bond strength occur under load

Engineering Contradiction:
Improvesealing effectVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent combines hollow glass microspheres with a polymer matrix (polyacrylate, polyurethane, or epoxy) to create a composite foam material. The glass microspheres provide the closed-cell structure for sealing, while the polymer matrix provides mechanical strength and cohesion. This composite approach allows both functions to coexist without compromising either sealing or mechanical performance.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If expandable hollow microspheres with thermoplastic polymer shell are used to improve adaptability and cohesive strength, then adaptability to surface conditions and cohesive strength are improved, but thickness consistency deteriorates due to manufacturing tolerances

Engineering Contradiction:
Improveadaptability to surface conditionsVSAvoidthickness consistency
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent specifies precise parameter ranges for the foam composition: 30-70 wt% polymer matrix, 30-70 wt% hollow microspheres, and controlled foam expansion ratios. By controlling these parameters and using non-expandable glass microspheres instead of expandable ones, the invention achieves consistent thickness while maintaining adaptability through the foam's inherent compliance.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If foamed adhesive layers are used to achieve micro-rough surfaces for non-destructive removability and repositionability, then repositionability is improved, but bond strength and peel strength are significantly reduced

Engineering Contradiction:
ImproverepositionabilityVSAvoidbond strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent creates a composite foam adhesive where the polymer matrix provides strong bonding properties (polyacrylate for adhesion, polyurethane for cohesive strength, or epoxy for high-strength bonding) while the hollow microsphere structure provides the micro-rough surface for repositionability. This composite structure allows simultaneous achievement of strong bond and easy repositioning.

Inventive Principle:
Principle #40Composite materials

4Adaptability or versatility

If carrier layer is foamed with microballoons to provide adaptability, then adaptability to surface conditions is improved, but thickness uniformity deteriorates due to deviations in average carrier thickness

Engineering Contradiction:
Improveadaptability to surface conditionsVSAvoidthickness uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent allows the foam structure to provide local adaptability through its compressed and expanded cell regions, while the overall thickness is controlled by the rigid polymer matrix framework. The hollow microspheres distribute stress locally without compromising global thickness uniformity, as the matrix maintains structural integrity throughout the layer.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves higher bonding strength and improved compression hardness, ensuring the foam is more adaptable and resilient, addressing the limitations of previous technologies by maintaining cohesive fracture patterns and adaptability to different surface conditions.

Implementation Method 1

microballoons filled with low-boiling liquids or liquefied gas, which expands to form a stable, closed-cell structure

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

microballoons filled with low-boiling liquids or liquefied gas

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP2796490B1Dually foamed polymer composition
Publication Date: 2018.05.02 TESA SE
  • EP2796490B1 patent drawingFigure 1
  • EP2796490B1 patent drawingFigure 2
  • EP2796490B1 patent drawingFigure 3

AI summary

The aim is to provide a polymer foam with high bond strength and improved compression strength. This is achieved by the polymer foam comprising cavities formed by microballoons as well as 2 to 20 vol.%, based on the total volume of the polymer foam, cavities enclosed by the polymer foam matrix. The application also relates to a method for producing a polymer foam according to the invention.