Ultrathin Polymeric Interface Films for IC Adhesion Without Thermal Resistance

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Solution Overview

Problem

Integrated circuit devices with high aspect ratio surfaces face challenges in conformal deposition of adhesion promotion materials, leading to thermal resistance and reduced efficiency in high-speed input/output applications due to thick adhesive layers and surface roughening.

Innovation Solution

The use of vacuum-based vapor deposition techniques, such as initiated chemical vapor deposition (iCVD), to deposit thin film polymers as adhesion promotion layers on smooth or rough surfaces, providing strong covalent bonding and acting as stress buffer layers without adding heat transfer resistance, and enabling uniform conformal deposition on high aspect ratio features.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If thick adhesive layers are used to promote adhesion, then adhesion strength is improved, but thermal resistance increases and heat transfer efficiency deteriorates

Engineering Contradiction:
Improveadhesion strengthVSAvoidthermal resistance
Core Design Contradiction:
StrengthVSLoss of energy

Solution Approach 1:

The patent applies this principle by using an ultrathin polymeric adhesive layer (few nanometers to sub-10 nm thickness) instead of thick adhesive layers. The thin film approach maintains adhesion promotion functionality while minimizing thermal resistance and heat transfer interference, directly resolving the contradiction between adhesion strength and thermal performance

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent changes the thickness parameter of the adhesive layer from conventional thick layers to ultrathin dimensions (few nm to sub-10 nm). This parameter change enables the layer to provide sufficient adhesion promotion while becoming thermally transparent, thus resolving the trade-off between adhesion strength and thermal resistance

Inventive Principle:
Principle #35Parameter changes

2Strength

If surface roughening is implemented to enhance adhesion, then adhesion promotion is improved, but device efficiency for high-speed input/output applications deteriorates

Engineering Contradiction:
Improveadhesion promotionVSAvoiddevice efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent uses an ultrathin polymeric film that can conform to both smooth and rough surfaces without requiring surface roughening. This thin film approach provides adhesion promotion while maintaining surface smoothness, thereby preserving device efficiency for high-speed applications

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The polymeric adhesive layer acts as an intermediary between the substrate and overlying materials, providing adhesion promotion through its molecular structure and bonding capabilities rather than through surface roughening. This mediator approach enables adhesion enhancement without compromising surface quality or device efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If conventional deposition techniques are used on high aspect ratio surfaces, then deposition capability is maintained, but conformal deposition quality deteriorates

Engineering Contradiction:
Improvedeposition capabilityVSAvoidconformal deposition quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent replaces conventional mechanical/physical deposition methods with a chemical vapor deposition process. The monomer vapor chemically reacts and polymerizes in situ on the substrate surface, enabling uniform conformal coating on high aspect ratio features where conventional techniques fail to achieve uniform coverage

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Strength

If additional curing steps are added to the deposition process, then adhesive performance is improved, but process complexity increases

Engineering Contradiction:
Improveadhesive performanceVSAvoidprocess complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent merges the deposition and curing steps into a single integrated process. The chemical vapor deposition process simultaneously deposits the polymeric adhesive layer and cures it through in situ polymerization, eliminating the need for separate curing steps while maintaining excellent adhesive performance and reducing process complexity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures strong adhesion between materials, reduces delamination, and maintains high thermal and mechanical stability, while allowing for efficient deposition on complex surfaces without the need for additional curing steps, thus addressing thermal and efficiency issues in integrated circuit manufacturing.

Implementation Method 1

vacuum-based vapor deposition techniques, such as initiated chemical vapor deposition (iCVD), to deposit thin film polymers

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Implementation Method 2

initiated chemical vapor deposition (iCVD)

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

The polymers may function as an adhesive/adhesion promotion layer between the surface and the dielectric material. When used as an adhesion layer, the polymer materials may provide very strong covalent bonding at the interface between two materials

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Data Source

PatentUS20240186136A1Polymeric films as an adhesive promotion/buffer layer at glass-dielectric or metal-dielectric interfaces
Publication Date: 2024.06.06 INTEL CORP
  • US20240186136A1 patent drawing
  • US20240186136A1 patent drawing
  • US20240186136A1 patent drawing

AI summary

In one embodiment, an integrated circuit apparatus (e.g., package substrate) includes a polymeric layer between a metal and a dielectric or between a metal and a glass. The polymeric layer may be conformally deposited using a vacuum-based vapor deposition technique, e.g., initiated chemical vapor deposition (iCVD).