Polyurethane-Polyurea Coating for UHMWPE Ballistic Armor

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Solution Overview

Problem

Polymeric materials used in blast and ballistic-resistant structures, such as UHMWPE and aramids, face issues like friability, surface chipping, and difficulty in achieving durable coatings due to low surface energy and reactivity, limiting their durability and aesthetic appeal, especially in high-traffic areas like aircraft and vehicle interiors.

Innovation Solution

A polymeric coating composition based on a plural component polymeric system, comprising a reactive blend of polymers and isocyanates, is applied to substrates like UHMWPE and aramids to enhance tensile strength, hardness, flexibility, and adhesion, providing a durable and wear-resistant antiballistic and blast-resistant surface without compromising the substrate's resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If polymeric materials like UHMWPE and aramids are used for blast and ballistic resistance, then high strength-to-weight ratio and impact resistance are achieved, but susceptibility to friability, surface chipping, and flaking occurs

Engineering Contradiction:
Improveballistic resistanceVSAvoidsurface durability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by combining the polymeric substrate (UHMWPE or aramid) with a polyurethane-polyurea coating layer. This composite structure integrates the high ballistic resistance of the polymeric substrate with the superior surface durability, wear resistance, and toughness of the polyurethane-polyurea coating, thereby resolving the contradiction between strength and surface reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the surface parameters of the polymeric substrate by applying a coating layer with different physical and chemical properties. The polyurethane-polyurea coating provides enhanced surface hardness, wear resistance, and flexibility, transforming the surface characteristics while maintaining the underlying ballistic protection.

Inventive Principle:
Principle #35Parameter changes

2Strength

If polymeric materials are used for armor panels, then high tensile strength and impact resistance are achieved, but difficulty in providing durable coated surfaces occurs due to low adhesion characteristics

Engineering Contradiction:
Improvetensile strengthVSAvoidcoating adhesion
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The polyurethane-polyurea coating acts as an intermediary layer between the polymeric substrate and the external environment. This intermediate layer provides improved adhesion characteristics, making it easier to apply and maintain durable coated surfaces on the low-adhesion polymeric materials while preserving their high tensile strength.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If armor panels are designed for high traffic areas, then protection is provided, but wear resistance is compromised due to gouging, chipping, and flaking

Engineering Contradiction:
Improveprotective functionVSAvoidservice life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The polyurethane-polyurea coating layer serves as a protective cushion applied beforehand to the armor panel surface. This pre-applied protective layer absorbs and distributes mechanical stresses from high-traffic usage, preventing direct contact between the substrate and damaging forces, thereby extending service life while maintaining protective function.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The coating layer modifies the surface parameters of the armor panel by providing enhanced wear resistance, surface hardness, and flexibility. These parameter changes enable the panel to withstand high-traffic conditions without gouging, chipping, or flaking, thus extending duration of action.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If a coating is applied to enhance wear resistance, then surface durability is improved, but ballistic or blast resistance may be compromised

Engineering Contradiction:
Improvewear resistanceVSAvoidballistic resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent carefully controls the parameters of the coating layer, including thickness (0.002 to 0.020 inches), composition, and curing conditions, to achieve the optimal balance between wear resistance and ballistic protection. The polyurethane-polyurea system provides enhanced surface durability while maintaining flexibility and toughness that preserve ballistic resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite structure of polymeric substrate plus polyurethane-polyurea coating creates a synergistic system where each layer contributes its superior properties. The substrate provides ballistic resistance while the coating provides wear resistance, and together they maintain both functions without compromise.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition significantly enhances the structural wear resistance and maintains the ballistic and blast resistance of the substrate, offering a durable and aesthetically appealing solution for high-traffic applications without compromising the substrate's integrity.

Implementation Method 1

The plural component system is composed of a reactive blend of at least one first component and at least one second component, wherein the first component consists essentially of a polymer and/or a blend of polymers... and the second component is an isocyanate or isocyanate quasi-prepolymer

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentEP2395314B8Blast and/or ballistic resistant member
Publication Date: 2019.10.02 LIFEPORT LLC

AI summary

A polymeric coating composition (22) for use in overlaying at least a portion of a substrate element (12) composed of a plural component polymeric system composed of a reactive blend of at least one first component and at least one second component, wherein the first component is consists essentially of a polymer and/or a blend of polymers present in an amount sufficient to impart a predetermined amount of tensile strength, hardness, flexibility and adhesive strength to the resulting polymeric coating (22) and the second component is an isocyanate or isocyanate quasi-prepolymer. The substrate element (12) is a blast-resistant polymeric material having low surface energy and/or low reactivity at or near the surface of the substrate. Also disclosed is a blast and/or ballistic- resistant construction element composed of a structure having the aforementioned polymeric material in overlying attached relationship thereto. The polymeric material of the structure has a substrate matrix containing at least one of ultrahigh molecular weight polyethylene, aramid materials, and the like.