Polyurethane Film for Bendable Circuit Boards

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Solution Overview

Problem

Current bendable wiring boards made from rigid materials like polyethylene terephthalate (PET) and polyimide (PI) lack adhesion and are prone to peeling due to stress, and existing stretchable electronics have low heat resistance, preventing sufficient conductivity and flexibility for wearable devices and biosensors.

Innovation Solution

A polyurethane film synthesized by reacting a long-chain polyol with a polyisocyanate, providing a storage elastic modulus of 20 to 200 MPa at 25°C, tensile strength of 20 to 80 MPa, and elongation at break of 500 to 900%, allowing for excellent contact feeling and resistance to bending, combined with circuit wiring for enhanced adhesion and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If rigid plastic materials like PET, PI, PEEK, PPS, PAR, PC, TAC, or CAP are used for flexible printed wiring, then structural strength and dimensional stability are improved, but the wiring board cannot return to its original shape after bending, has low adhesion between metal wiring and board, and metal wiring may peel off or break due to stress

Engineering Contradiction:
Improvestructural strengthVSAvoidadhesion between metal wiring and board
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the fundamental material parameter from rigid plastics to elastomers, transforming the mechanical properties from brittle to flexible. This allows the substrate to elastically deform and return to its original shape, preventing wiring breakage and peeling while maintaining structural integrity through the elastomer's inherent elasticity and recovery capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures where elastomer substrates are combined with metal wiring patterns. The elastomer provides flexibility and adhesion, while the metal wiring provides electrical conductivity. This composite approach resolves the contradiction by allowing the substrate to deform elastically without compromising the wiring's structural strength or adhesion

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If elastomeric materials are used for stretchable electronics, then flexibility and elasticity are improved, but heat resistance deteriorates, preventing heating at temperatures around 120°C which is required for sufficient sintering of conductive fine particles

Engineering Contradiction:
Improveflexibility and elasticityVSAvoidheat resistance
Core Design Contradiction:
Adaptability or versatilityVSTemperature

Solution Approach 1:

The patent modifies the thermal parameter of elastomeric materials by selecting or developing elastomers with enhanced heat resistance that can withstand temperatures around 120°C. This allows the material to maintain its flexibility and elasticity while achieving sufficient thermal stability for sintering conductive particles, thus resolving the contradiction between flexibility and heat resistance

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If conventional lithography technology is used for producing ICs, then manufacturing precision and performance are improved, but cost increases significantly compared to printing technologies

Engineering Contradiction:
Improvecircuit wiring precisionVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces the complex mechanical lithography system with a simpler printing technology system. Instead of using expensive vacuum processes and sophisticated lithography equipment, the invention employs printing methods to deposit conductive materials directly onto elastomer substrates, significantly reducing manufacturing cost while maintaining acceptable circuit wiring precision through the printing process's inherent capability to form fine patterns

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyurethane-based bendable wiring board offers excellent contact feeling, high flexibility, and resistance to bending and folding, maintaining conductivity and adhesion, suitable for wearable devices and biosensors with improved heat resistance and durability.

Implementation Method 1

a film composed of a polyurethane synthesized by allowing a long-chain polyol to react with a polyisocyanate

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Data Source

PatentUS11542377B2Bendable circuit board, expandable circuit board, and electronic device made therefrom
Publication Date: 2023.01.03 MITSUI CHEMICALS INC
  • US11542377B2 patent drawing
  • US11542377B2 patent drawing
  • US11542377B2 patent drawing

AI summary

Provided are an expandable or bendable circuit board having good body-contact feel, strong against bending and folding, and an electronic device made therefrom. The bendable circuit board includes: a film comprising a polyurethane synthesized by reacting a long-chain polyol with polyisocyanate and having a storage modulus at 25° C. of 20 to 200 MPa, a tensile strength of 20 to 80 MPa, and an elongation at break of 500 to 900%, and the temperature of which the storage elastic modulus reaches to 1 MPa is at 155° C. or higher; and circuit wiring formed in contact with a surface of the film. Alternatively, an expandable circuit board having the ratio ρ/ρ0 of the specific electrical resistance ρ of the circuit wiring when the circuit wiring is expanded to the specific electrical resistance (Ω·cm) ρ0 of the circuit wiring before the circuit wiring is expanded is within a range of 1.05 to 10.0.