Porous Second Electrode for OLED Dark Spot Prevention

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Solution Overview

Problem

Organic light-emitting display devices are prone to deterioration due to moisture and oxygen sensitivity, leading to reduced lifetime and the formation of dark spots, especially under varying temperatures and external impacts.

Innovation Solution

Incorporating a porous second electrode with pores to prevent localized impurity concentration, combined with a filler and getter materials to absorb outgases and a porous separation layer to mitigate direct contact issues, which delays the occurrence of dark spots and extends the device's lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a dense second electrode is used, then the device structure is simple and manufacturing is easier, but impurities become localized concentrated in specific areas causing dark spots

Engineering Contradiction:
Improvedevice lifetimeVSAvoidelectrode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies porous materials by forming the second electrode with a porous structure containing numerous pores. This porous configuration allows impurities to be distributed throughout the pores rather than localized in specific areas, preventing dark spot formation while maintaining electrode functionality. The porous structure resolves the contradiction by sacrificing some structural simplicity to gain improved impurity distribution and device reliability.

Inventive Principle:
Principle #31Porous materials

2Adaptability or versatility

If the organic light-emitting device is exposed to moisture and oxygen, then the device can operate in ambient conditions, but deterioration is facilitated and lifetime is reduced

Engineering Contradiction:
Improveambient operation capabilityVSAvoiddevice lifetime
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent employs composite materials by combining the organic light-emitting layer with inorganic encapsulation layers and porous electrode structures. This composite approach creates a multi-layered system where different materials provide complementary functions: the organic layer enables ambient operation while the inorganic and porous structures provide protection against moisture and oxygen, resolving the contradiction between adaptability and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates an inert environment by forming encapsulation layers and using porous electrode structures that reduce exposure to harmful substances. The porous second electrode and encapsulation structures collectively create a protected environment that limits moisture and oxygen contact, allowing the device to maintain both ambient operation capability and extended lifetime.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Temperature

If the temperature increases to 30-60°C, then the device can operate in warmer environments, but the lifetime is reduced by about 20 times

Engineering Contradiction:
Improveoperating temperature rangeVSAvoiddevice lifetime
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The porous second electrode structure provides thermal management benefits by facilitating heat dissipation through the porous network. This helps maintain more stable operating temperatures even in warmer environments, mitigating the accelerated deterioration that would normally occur at elevated temperatures and allowing the device to maintain reliability across a broader temperature range.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively disperses impurities within the porous structure, reducing localized damage and extending the organic light-emitting display apparatus' lifetime by preventing the formation of progressive dark spots, thereby enhancing its reliability and durability.

Implementation Method 1

a porous second electrode disposed on the intermediate layer. Pores of the porous second electrode prevent localized concentration of impurities in the porous second electrode

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 2

combined with a filler and getter materials to absorb outgases

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10944071B2Organic light-emitting display apparatus and method of manufacturing the same
Publication Date: 2021.03.09 SAMSUNG DISPLAY CO LTD
  • US10944071B2 patent drawing
  • US10944071B2 patent drawing
  • US10944071B2 patent drawing

AI summary

A an organic light-emitting display apparatus, including a first substrate, a display unit having a plurality of organic light-emitting devices that is formed on the first substrate, a second substrate disposed on the display unit, and a filler included between the first substrate and the second substrate. The organic light-emitting device includes a first electrode formed on the first substrate, an intermediate layer that is disposed on the first electrode and includes an organic emission layer, and a porous second electrode disposed on the intermediate layer.