PRAM Phase-Change Layer Bismuth Doping for Fast Crystallization

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Solution Overview

Problem

Conventional phase-change random access memories (PRAMs) face challenges with high crystallization temperatures and slow crystallization speeds, leading to difficulties in achieving high operational speeds due to the need for high reset currents and long set times.

Innovation Solution

A PRAM with a phase-change layer made of materials like Ge2(Sb1-xBix)2Te5 or Ge3Bi2Te6, which have lower crystallization temperatures (between 100° C and 150° C) and faster crystallization times (between 1 ns and 50 ns), allowing for reduced programming currents and improved data storage efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional GST phase-change material is used in PRAM, then data storage capability is achieved, but crystallization temperature is high and crystallization speed is slow

Engineering Contradiction:
Improvecrystallization temperatureVSAvoidcrystallization speed
Core Design Contradiction:
TemperatureVSSpeed

Solution Approach 1:

The patent modifies the chemical composition parameters of the phase-change material by incorporating Bismuth (Bi) into the Ge-Sb-Te system, creating Ge2(Sb1-xBix)2Te5 or Ge3Bi2Te6 compositions. This compositional parameter change results in a lower crystallization temperature range (100-150°C) and faster crystallization speed (1-50 ns) compared to conventional GST materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite phase-change material system by combining multiple elements (Ge, Sb, Te, and Bi) in specific ratios. The Ge2(Sb1-xBix)2Te5 and Ge3Bi2Te6 compositions represent composite materials where Bismuth acts as a dopant that modifies the crystallization properties of the base GST material, achieving both lower temperature and faster speed

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If conventional GST phase-change material is used in PRAM, then data storage is enabled, but reset current requirement is high

Engineering Contradiction:
Improveprogramming currentVSAvoiddata storage reliability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the electrical and thermal parameters of the phase-change material through compositional modification. The Ge2(Sb1-xBix)2Te5 and Ge3Bi2Te6 materials exhibit modified electrical conductivity and thermal properties that enable achieving the necessary resistance state changes (amorphous to crystalline) with lower current pulses, reducing the programming current requirement while maintaining data storage reliability

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If conventional GST phase-change material is used in PRAM, then memory function is achieved, but set time is long

Engineering Contradiction:
Improveset timeVSAvoidoperational speed
Core Design Contradiction:
Loss of timeVSProductivity

Solution Approach 1:

The patent achieves faster set time (crystallization time) by modifying the material's kinetic parameters through compositional changes. The Ge2(Sb1-xBix)2Te5 and Ge3Bi2Te6 materials exhibit enhanced atomic mobility and faster phase transition kinetics, enabling crystallization to complete within 1-50 nanoseconds, which directly improves operational speed and reduces the time penalty for data writing operations

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables faster data storage and reduced programming currents, enhancing the operational speed and data integrity of PRAMs by utilizing materials with lower crystallization temperatures and shorter crystallization times.

Implementation Method 1

a phase-change layer formed of a material having a lower crystallization temperature and quicker information storing time because of a faster crystallization speed than a conventional GST phase-change material

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

when an electrical pulse is applied to the phase-change material, a state of the phase-change material changes between crystalline and amorphous states according to heat generated in a localized area

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

heat generated in a localized area

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS8767450B2Memory controllers to refresh memory sectors in response to writing signals and memory systems including the same
Publication Date: 2014.07.01 SAMSUNG ELECTRONICS CO LTD
  • US8767450B2 patent drawing
  • US8767450B2 patent drawing
  • US8767450B2 patent drawing

AI summary

A memory system includes a memory cell array having a plurality of memory sectors. Each memory sector includes a plurality of memory cells. The memory system further includes a controller configured to write data to the memory cell array in response to a writing signal. The controller is further configured to refresh a memory sector among the plurality of memory sectors each time a writing signal is provided. When N (N is a positive integer) memory cells are programmed, a programming current is less than or equal to about 0.75 mA*N.